tri-μ-ethoxybis[(η-benzene)ruthenium(II)] tetraphenylborate

Base Information

• Chemical Name: tri-μ-ethoxybis[(η-benzene)ruthenium(II)] tetraphenylborate
• CAS No.: 68403-01-0
• Molecular Formula: C₁₈H₂₇O₃Ru₂*C₂₄H₂₀B
• Molecular Weight: 812.784
• Mol file: 68403-01-0.mol

Synonyms:

Chemical Property of tri-μ-ethoxybis[(η-benzene)ruthenium(II)] tetraphenylborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tri-μ-ethoxybis[(η-benzene)ruthenium(II)] tetraphenylborate

There total 3 articles about tri-μ-ethoxybis[(η-benzene)ruthenium(II)] tetraphenylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

dichloro(benzene)ruthenium(II) dimer (37366-09-9) + sodium tetraphenyl borate (143-66-8) → tri-μ-ethoxybis[(η-benzene)ruthenium(II)] tetraphenylborate (68403-01-0)

Guidance literature:

With NaNH₂; C₂H₅OH; In acetonitrile; byproducts: NaCl; (N2); complex added to suspn. of NaNH2 in CH3CN, shaken for 24 h, filtered (celite), evapd., treated with EtOH soln. of NaBPh4; ppt. washed with EtOH, dried in vac.; elem. anal.;

DOI:10.1016/0022-328X(84)85040-8

Reference yield:

tri-μ-hydroxobis{(η-benzene)ruthenium(II)} tetraphenylborate-acetone (1/1) → tri-μ-ethoxybis[(η-benzene)ruthenium(II)] tetraphenylborate (68403-01-0)

Guidance literature:

With C₂H₅OH; In ethanol; Ru complex refluxed in EtOH under N2; elem. anal.;

DOI:10.1016/S0022-328X(00)86723-6

Reference yield:

dichloro(benzene)ruthenium(II) dimer (37366-09-9) + sodium ethanolate (141-52-6) + sodium tetraphenyl borate (143-66-8) → tri-μ-ethoxybis[(η-benzene)ruthenium(II)] tetraphenylborate (68403-01-0)

Guidance literature:

In methanol; Ru complex added to freshly prepared soln. of NaOCH2CH3 in MeOH, soln. gently warmed under N2, NaBPh4 added; washing (MeOH), air drying; elem. anal.;

DOI:10.1016/S0022-328X(00)86723-6

upstream raw materials:

dichloro(benzene)ruthenium(II) dimer

sodium tetraphenyl borate

sodium ethanolate

Refernces

• 1、 Arthur, T.,Robertson, D.R.,Tocher, D.A.,Stephenson, T.A.. "SYNTHESIS OF BINUCLEAR HYDROXO- AND ALKOXO-BRIDGED ARENE COMPLEXES OF RUTHENIUM(II) AND OSMIUM(II)". . p. 389 - 400. Retrieved 2007/10/02.