tris-N-(5-bromo-salicylidene)aminoguanidine hydrochloride

Base Information

• Chemical Name: tris-N-(5-bromo-salicylidene)aminoguanidine hydrochloride
• CAS No.: 955951-82-3
• Molecular Formula: C₂₂H₁₇Br₃N₆O₃*ClH
• Molecular Weight: 689.588
• Mol file: 955951-82-3.mol

Synonyms:

Chemical Property of tris-N-(5-bromo-salicylidene)aminoguanidine hydrochloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tris-N-(5-bromo-salicylidene)aminoguanidine hydrochloride

There total 1 articles about tris-N-(5-bromo-salicylidene)aminoguanidine hydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triaminoguanidine hydrochloride (5329-29-3) + 5-bromosalicyclaldehyde (1761-61-1) → tris-N-(5-bromo-salicylidene)aminoguanidine hydrochloride (955951-82-3)

Guidance literature:

In ethanol; water;

DOI:10.1002/anie.200461800

Reference yield: 47.0%

tris-N-(5-bromo-salicylidene)aminoguanidine hydrochloride (955951-82-3) + nickel(II) perchlorate hexahydrate + 2,4,6-tris(2-pyridyl)-1,3,5-triazine (3682-35-7) + water (7732-18-5) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → tris-N-(5-bromo-salicylidene(2,4,6-tris(2-pyridyl)-1,3,5-triazine)nickel(II))aminoguanidine perchlorate-dimethylformamide-water (1/1.5/7)

Guidance literature:

With triethylamine; In methanol; N,N-dimethyl-formamide; to a soln. of guanidine compd. (DMF, excess) added a soln. of Ni salt (methanol), followed by addition of base, stirred for 15 min, a soln. of triazine compd. (methanol, 1 equiv.) added stepwise, stirred for 15 min; filtered, allowed to stand at room temp., diethyl ether slowly diffused,ppt. dried (air); elem. anal.;

DOI:10.1016/j.ica.2007.04.014

upstream raw materials:

triaminoguanidine hydrochloride

5-bromosalicyclaldehyde

Refernces