bis(6-p-tolyl-2,2'-bipyridine)copper(I) hexafluorophosphate

Base Information

• Chemical Name: bis(6-p-tolyl-2,2'-bipyridine)copper(I) hexafluorophosphate
• CAS No.: 889663-82-5
• Molecular Formula: C₃₄H₂₈CuN₄*F₆P
• Molecular Weight: 701.133
• Mol file: 889663-82-5.mol

Synonyms:

Chemical Property of bis(6-p-tolyl-2,2'-bipyridine)copper(I) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of bis(6-p-tolyl-2,2'-bipyridine)copper(I) hexafluorophosphate

There total 1 articles about bis(6-p-tolyl-2,2'-bipyridine)copper(I) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + 6-p-tolyl-2,2'-bipyridine (86696-22-2) → bis(6-p-tolyl-2,2'-bipyridine)copper(I) hexafluorophosphate (889663-82-5)

Guidance literature:

In acetonitrile; under Ar; Cu complex and ligand dissolved in MeCN; stirred at room temp.for 10-30 min; concd. in vac.;

DOI:10.1039/b515540a

Reference yield: 91.0%

bis(6-p-tolyl-2,2'-bipyridine)copper(I) hexafluorophosphate (889663-82-5) + cinchonidinium Δ-tris(tetrachlorobenzenediolato)phosphate(V) → bis(6-p-tolyl-2,2'-bipyridine)copper(I) Δ-tris(tetrachlorobenzenediolato)phosphate(V) (889663-89-2)

Guidance literature:

In dichloromethane; acetone; under Ar; Cu complex and cinchonidinium salt dissolved in CH2Cl2-acetone; stirred for 30 min; evapd. to dryness; purified by column chromy. (silica gel, CH2Cl2);

DOI:10.1039/b515540a

upstream raw materials:

tetrakis(actonitrile)copper(I) hexafluorophosphate

6-p-tolyl-2,2'-bipyridine

Downstream raw materials:

bis(6-p-tolyl-2,2'-bipyridine)copper(I) Δ-tris(tetrachlorobenzenediolato)phosphate(V)

Refernces