RhCl(CO)2((C₆H₅)2PC₄H₃S)2

Base Information

• Chemical Name: RhCl(CO)2((C₆H₅)2PC₄H₃S)2
• CAS No.: 93708-73-7
• Molecular Formula: C₃₄H₂₆ClO₂P₂RhS₂
• Molecular Weight: 731.017
• Mol file: 93708-73-7.mol

Synonyms:

Chemical Property of RhCl(CO)2((C₆H₅)2PC₄H₃S)2

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of RhCl(CO)2((C₆H₅)2PC₄H₃S)2

There total 2 articles about RhCl(CO)2((C₆H₅)2PC₄H₃S)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + diphenyl(2-thienyl)phosphine (61157-16-2) → RhCl(CO)2((C6H5)2PC4H3S)2 (93708-73-7)

Guidance literature:

With carbon monoxide; In dichloromethane; Rh-complex under CO was added to soln. of ligand in CH2Cl2, EtOH was added; solvent was evapd.; elem. anal.;

Reference yield:

RhCl(CO)((C6H5)2PC4H3S)2 (93708-74-8) → RhCl(CO)2((C6H5)2PC4H3S)2 (93708-73-7)

Guidance literature:

In dichloromethane; Rh-complex was dissolved in CH2Cl2, EtOH was added; solvent was slow evapd. under CO;

Reference yield:

RhCl(CO)2((C6H5)2PC4H3S)2 (93708-73-7) → RhCl(CO)((C6H5)2PC4H3S)2 (93708-74-8)

Guidance literature:

In dichloromethane; Rh-complex was dissolved in CH2Cl2 under N2, then layer of EtOH was added; slow evapd. of CH2Cl2; elem. anal.;

upstream raw materials:

RhCl(CO)((C₆H₅)2PC₄H₃S)2

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

diphenyl(2-thienyl)phosphine

Downstream raw materials:

RhCl(CO)((C₆H₅)2PC₄H₃S)2

Refernces