4-Dimethylaminoazobenzene amine N-oxide

Base Information

• Chemical Name: 4-Dimethylaminoazobenzene amine N-oxide
• CAS No.: 118527-25-6
• Molecular Formula: C₁₄H₁₅N₃O
• Molecular Weight: 241.293
• DSSTox Substance ID: DTXSID601031094,DTXSID601043639
• Nikkaji Number: J60.422D
• Mol file: 118527-25-6.mol

Synonyms:DMAB N-oxide;N,N-dimethyl-4-aminoazobenzene N-oxide

Chemical Property of 4-Dimethylaminoazobenzene amine N-oxide

Chemical Property:

• XLogP3: 3.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 241.121512110
• Heavy Atom Count: 18
• Complexity: 277

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[N+](C)(C1=CC=C(C=C1)N=NC2=CC=CC=C2)[O-]

Technology Process of 4-Dimethylaminoazobenzene amine N-oxide

There total 5 articles about 4-Dimethylaminoazobenzene amine N-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

methyl yellow (60-11-7) → 4-(methylamino)azobenzene (42472-83-3) + N,N-dimethyl-4-(phenyl-trans-azo)-aniline-N-oxide (118527-25-6) + N-formyl-N-methyl-4-aminoazobenzene (102840-90-4)

Guidance literature:

With 2,2-dimethoxy-2-phenylacetophenone; oxygen; In methanol; Product distribution; Mechanism; Quantum yield; Irradiation; photodecomposition, quenching effect of 2,3-dimethylbutene; other solvent; other reagents;

Reference yield:

methyl yellow (60-11-7) → 4-(methylamino)azobenzene (42472-83-3) + N,N-dimethyl-4-(phenyl-trans-azo)-aniline-N-oxide (118527-25-6)

Guidance literature:

With 2,2-dimethoxy-2-phenylacetophenone; oxygen; In benzene; Yield given. Yields of byproduct given; Irradiation;

Reference yield:

Perbenzoic acid (93-59-4) + methyl yellow (60-11-7) → N,N-dimethyl-4-(phenyl-trans-azo)-aniline-N-oxide (118527-25-6)

Guidance literature:

With chloroform;

DOI:10.1016/0040-4020(59)80067-3

upstream raw materials:

3-chloro-benzenecarboperoxoic acid

methyl yellow

Perbenzoic acid

Downstream raw materials:

N,N-dimethyl-4-((Z)-phenyl-ONN-azoxy)-aniline-N-oxide

Refernces

• 1、 Albini, Angelo,Fasani, Elisa,Pietra, Silvio. "PHOTOCHEMICAL DECOMPOSITION OF SOME 4-(DIALKYLAMINO)AZOBENZENES IN AERATED SOLUTION". . p. 257 - 262. Retrieved 2007/10/02.