sodium dihydronaphthylide

Base Information

• Chemical Name: sodium dihydronaphthylide
• CAS No.: 13269-57-3
• Molecular Formula: C₁₀H₈*2Na
• Molecular Weight: 174.153
• Mol file: 13269-57-3.mol

Synonyms:

Chemical Property of sodium dihydronaphthylide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of sodium dihydronaphthylide

There total 3 articles about sodium dihydronaphthylide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

naphthalene (91-20-3,71998-51-1,72931-45-4) → naphthalene radical anion sodium salt (3481-12-7,13269-57-3,116346-73-7)

Guidance literature:

With sodium; In tetrahydrofuran; for 24h;

DOI:10.1021/jo00150a003

Reference yield:

naphthalene (91-20-3,71998-51-1,72931-45-4) + sodium (7440-23-5) → naphthalene radical anion sodium salt (3481-12-7,13269-57-3,116346-73-7)

Guidance literature:

In tetrahydrofuran; Inert atmosphere; Schlenk technique;

DOI:10.1021/ic301675t

Reference yield:

naphthalene (91-20-3,71998-51-1,72931-45-4) → naphthalene radical anion sodium salt (3481-12-7,13269-57-3,116346-73-7)

Guidance literature:

In tetrahydrofuran; for 3h; Ambient temperature;

upstream raw materials:

naphthalene

sodium

Downstream raw materials:

sodium formate

bis(isopropylcyclopentadienyl)titanium dichloride

(hexacarbonyl)vanadinate^(1-)

(Ph₄As)(Ph₃SnTi(CO)4(dmpe))

Refernces

• 1、 Deegan, Meaghan M.,Peters, Jonas C.. "O -Functionalization of a cobalt carbonyl generates a terminal cobalt carbyne". supporting information. p. 9531 - 9534. Retrieved 2019/08/15.
• 2、 Sánchez-Cantalejo, Fernando,Priest, Joshua D.,Davies, Paul W.. "A Gold Carbene Manifold to Prepare Fused γ-Lactams by Oxidative Cyclisation of Ynamides". supporting information. p. 17215 - 17219. Retrieved 2018/11/10.