[α,α,α,α-meso-tetrakis(o-pivalamidophenyl)porphinato]iron(II)-mono(1-dodecyl-2-methylimidazole) complex

Base Information

• Chemical Name: [α,α,α,α-meso-tetrakis(o-pivalamidophenyl)porphinato]iron(II)-mono(1-dodecyl-2-methylimidazole) complex
• CAS No.: 81737-55-5
• Molecular Formula: C₈₀H₉₄FeN₁₀O₄
• Molecular Weight: 1315.54
• Mol file: 81737-55-5.mol

Synonyms:

Chemical Property of [α,α,α,α-meso-tetrakis(o-pivalamidophenyl)porphinato]iron(II)-mono(1-dodecyl-2-methylimidazole) complex

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [α,α,α,α-meso-tetrakis(o-pivalamidophenyl)porphinato]iron(II)-mono(1-dodecyl-2-methylimidazole) complex

There total 1 articles about [α,α,α,α-meso-tetrakis(o-pivalamidophenyl)porphinato]iron(II)-mono(1-dodecyl-2-methylimidazole) complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-n-dodecyl-2-methylimidazole (5709-29-5) + [α,α,α,α-meso-tetrakis(o-pivalamidophenyl)porphinato]iron(III) bromide (52215-70-0,173936-95-3,1227639-02-2) → [α,α,α,α-meso-tetrakis(o-pivalamidophenyl)porphinato]iron(II)-mono(1-dodecyl-2-methylimidazole) complex (81737-55-5,92418-95-6)

Guidance literature:

With phosphate buffer; phosphatidylcholine; ascorbic acid; In dichloromethane; water; Sonication; educts and phosphatidylcholine mixed in CH2Cl2, evapd. in vac., oxygen-free pH 7.0 M/15 phosphate buffer soln. added, ultrasonicated in ice-water bath, 20-fold mole excess of L-ascorbic acid added under N2, incubated at room temp. for 2 h; not isolated; detected by UV;

DOI:10.1246/bcsj.57.776

Reference yield:

[α,α,α,α-meso-tetrakis(o-pivalamidophenyl)porphinato]iron(II)-mono(1-dodecyl-2-methylimidazole) complex (81737-55-5,92418-95-6) → [α,α,α,α-meso-tetrakis(o-pivalamidophenyl)porphinato]iron(II)-mono(1-dodecyl-2-methylimidazole) dioxygen complex

Guidance literature:

With phosphate buffer; phosphatidylcholine; In water; bubbling O2 through soln. of Fe complex in phosphate buffer; not isolated; detected by UV;

DOI:10.1246/bcsj.57.776

upstream raw materials:

1-n-dodecyl-2-methylimidazole

[α,α,α,α-meso-tetrakis(o-pivalamidophenyl)porphinato]iron(III) bromide

Refernces