(1,2-bis(diphenylphosphino)ethane)Ni(PhNC(S)N(CH₂CH₂)2S)BPh₄

Base Information

• Chemical Name: (1,2-bis(diphenylphosphino)ethane)Ni(PhNC(S)N(CH₂CH₂)2S)BPh₄
• CAS No.: 1279624-59-7
• Molecular Formula: C₂₄H₂₀B*C₃₇H₃₇N₂NiP₂S₂
• Molecular Weight: 1013.72
• Mol file: 1279624-59-7.mol

Synonyms:

Chemical Property of (1,2-bis(diphenylphosphino)ethane)Ni(PhNC(S)N(CH₂CH₂)2S)BPh₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,2-bis(diphenylphosphino)ethane)Ni(PhNC(S)N(CH₂CH₂)2S)BPh₄

There total 1 articles about (1,2-bis(diphenylphosphino)ethane)Ni(PhNC(S)N(CH₂CH₂)2S)BPh₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

N-phenyl-N’-thiomorpholinethiourea (21427-52-1) + sodium tetraphenyl borate (143-66-8) + nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → (1,2-bis(diphenylphosphino)ethane)Ni(PhNC(S)N(CH2CH2)2S)BPh4 (1279624-59-7)

Guidance literature:

With NEt₃; In methanol; mixt. of Ni acetate and dppe in MeOH; stirred, gently warmed for 5 min; thiourea deriv. added; aq. NEt3 added, mixt. warmed briefly to ca. 60°C; NaBPh4 added to filtrate; allowed to cool to room temp.; ppt. filtered, washed with cold MeOH, dried under vac.; elem. anal.;

DOI:10.1016/j.ica.2010.12.011

upstream raw materials:

N-phenyl-N’-thiomorpholinethiourea

sodium tetraphenyl borate

nickel diacetate

1,2-bis-(diphenylphosphino)ethane

Refernces