(1-Methylpentyl)magnesium chloride

Base Information

• Chemical Name: (1-Methylpentyl)magnesium chloride
• CAS No.: 13406-08-1
• Molecular Formula: C6H13ClMg
• Molecular Weight: 144.927
• Hs Code.: 2931900090
• Mol file: 13406-08-1.mol

Synonyms:1-Methylpentylmagnesiumchlorid;2-hexylmagnesium chloride;Magnesium,chloro(1-methylpentyl);(1-methyl-pentyl)-magnesium chloride;

Chemical Property of (1-Methylpentyl)magnesium chloride

Chemical Property:

• PSA: 0.00000
• LogP: -0.59520

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1-Methylpentyl)magnesium chloride

There total 1 articles about (1-Methylpentyl)magnesium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-chlorohexane (638-28-8) → 1-Methylpentylmagnesiumchlorid (13406-08-1)

Guidance literature:

With diethyl ether;

Reference yield:

1-Methylpentylmagnesiumchlorid (13406-08-1) → 2-chlorohexane (638-28-8)

Guidance literature:

Multi-step reaction with 3 steps

1: 1.) O₂, 2.) aq. H₂SO₄ / 1.) diethyl ether, -65 deg C

2: 1.) n-octane, manganese stearate, 2.) LiAlH₄ / 1.) 125 deg C, 10 h, 2.) THF, reflux, 1 h

3: thionyl chloride, pyridine

With pyridine; lithium aluminium tetrahydride; thionyl chloride; octane; sulfuric acid; oxygen; manganese(II) stearate;

DOI:10.1002/prac.19943360109

Reference yield:

1-Methylpentylmagnesiumchlorid (13406-08-1) → 1-hexene (592-41-6,25067-06-5) + cis-2-hexene (7688-21-3) + trans-2-hexene (4050-45-7)

Guidance literature:

With ethene; nickel dichloride; In diethyl ether; at 0 ℃; for 1h; Yield given. Yields of byproduct given;

upstream raw materials:

2-chlorohexane

Downstream raw materials:

1-hexene

cis-2-hexene

trans-2-hexene

2-chlorohexane