triisopropylsilyl Methacrylate

Base Information

• Chemical Name: triisopropylsilyl Methacrylate
• CAS No.: 134652-60-1
• Molecular Formula: C13H26O2Si
• Molecular Weight: 242.43000
• Mol file: 134652-60-1.mol

Synonyms:2-Propenoic acid,2-methyl-,tris(1-methylethyl)silyl ester;

Chemical Property of triisopropylsilyl Methacrylate

Chemical Property:

• Vapor Pressure: 3.9-5.1hPa at 20-25℃
• Boiling Point: 249.6±9.0 °C(Predicted)
• PSA: 26.30000
• Density: 0.870±0.06 g/cm3(Predicted)
• LogP: 4.28120

Purity/Quality:

99.9% ^*data from raw suppliers

Triisopropylsilylmethacrylate 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of triisopropylsilyl Methacrylate

There total 5 articles about triisopropylsilyl Methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + chlorotriisopropylsilane (6485-79-6) → triisopropylsilyl methacrylate (134652-60-1)

Guidance literature:

With triphenylphosphine; In N,N-dimethyl-formamide; at 20 ℃; for 14h;

DOI:10.1080/00397910701465669

Reference yield: 85.8%

sodium methacrylate (5536-61-8) + C18H43O4PSi2 → triisopropylsilyl methacrylate (134652-60-1)

Guidance literature:

With 10H-phenothiazine; tert-butylhydroquinone; at 10 ℃; for 24h;

Reference yield: 57.0%

triisopropylsilyl chloride (13154-24-0) + sodium methacrylate (5536-61-8) → triisopropylsilyl methacrylate (134652-60-1)

Guidance literature:

With 2,6-di-tert-butyl-4-methyl-phenol; In tetrahydrofuran; at 0 - 20 ℃; for 25.5h; Inert atmosphere;

DOI:10.1021/ma202155b

upstream raw materials:

poly(methacrylic acid)

chlorotriisopropylsilane

triisopropylsilyl chloride

sodium methacrylate

Refernces

• 1、 -. "Three hydrocarbyl silicon-based acrylate or three hydrocarbyl silicon-based methyl acrylate preparation method". Paragraph 0026; 0028. . Retrieved 2020/05/08.
• 2、 Liu, Guo-Bin,Zhao, Hong-Yun,Thiemann, Thies. "Two new catalysts for the dehydrogenative coupling reaction of carboxylic acids with silanes - Convenient methods for an atom-economical preparation of silyl esters". . p. 2717 - 2727. Retrieved 2008/02/12.