(E)-pent-1-ene-1,3-diyldibenzene

Base Information

• Chemical Name: (E)-pent-1-ene-1,3-diyldibenzene
• CAS No.: 189322-54-1
• Molecular Formula: C₁₇H₁₈
• Molecular Weight: 222.33
• Mol file: 189322-54-1.mol

Synonyms:

Chemical Property of (E)-pent-1-ene-1,3-diyldibenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-pent-1-ene-1,3-diyldibenzene

There total 12 articles about (E)-pent-1-ene-1,3-diyldibenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

(E)-1-phenyl-1-penten-3-ol acetate (94421-30-4,113334-99-9,113334-98-8) + phenylboronic acid (98-80-6) → (E)-pent-1-ene-1,3-diyldibenzene (189322-54-1,224561-71-1)

Guidance literature:

With potassium fluoride; In methanol; at 70 ℃; for 3h;

DOI:10.1002/anie.201103799

Reference yield: 99.0%

(E)-1-phenyl-1-penten-3-ol acetate (94421-30-4,113334-99-9,113334-98-8) + sodium tetraphenyl borate (143-66-8) → (E)-pent-1-ene-1,3-diyldibenzene (189322-54-1,224561-71-1)

Guidance literature:

With metalloprotein-inspired polymeric imidazole/palladium; In water; at 50 ℃; for 8h;

DOI:10.1002/anie.201103799

Reference yield: 97.0%

(E)-3-(methoxycarbonyloxy)-1-phenyl-1-pentene (1357175-60-0) + sodium tetraphenyl borate (143-66-8) → (E)-pent-1-ene-1,3-diyldibenzene (189322-54-1,224561-71-1)

Guidance literature:

With poly[(N-vinylimidazole)-co-(N-isopropylacrylamide)]-based palladium catalyst; In water; isopropyl alcohol; at 50 ℃; for 4h;

DOI:10.1021/ja210772v

upstream raw materials:

(E)-1-phenyl-1-penten-3-ol acetate

sodium tetraphenyl borate

phenylboronic acid

1-phenyl-pent-1-en-3-ol

Refernces

• 1、 Stokes, Benjamin J.,Bischoff, Amanda J.,Sigman, Matthew S.. "Pd(quinox)-catalyzed allylic relay Suzuki reactions of secondary homostyrenyl tosylates via alkene-assisted oxidative addition". . p. 2336 - 2339. Retrieved 2014/05/20.
• 2、 Stokes, Benjamin J.,Opra, Susanne M.,Sigman, Matthew S.. "Palladium-catalyzed allylic cross-coupling reactions of primary and secondary homoallylic electrophiles". supporting information; experimental part. p. 11408 - 11411. Retrieved 2012/09/05.