4'-O-hexanoylgenistein-7-yl-2,3,4-tri-O-benzoyl-6-deoxy-α-L-talopyranoside

Base Information

• Chemical Name: 4'-O-hexanoylgenistein-7-yl-2,3,4-tri-O-benzoyl-6-deoxy-α-L-talopyranoside
• CAS No.: 1260367-71-2
• Molecular Formula: C₄₈H₄₂O₁₃
• Molecular Weight: 826.854
• Mol file: 1260367-71-2.mol

Synonyms:

Chemical Property of 4'-O-hexanoylgenistein-7-yl-2,3,4-tri-O-benzoyl-6-deoxy-α-L-talopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4'-O-hexanoylgenistein-7-yl-2,3,4-tri-O-benzoyl-6-deoxy-α-L-talopyranoside

There total 6 articles about 4'-O-hexanoylgenistein-7-yl-2,3,4-tri-O-benzoyl-6-deoxy-α-L-talopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5,4'-di-O-hexanoyl-genistein (918158-58-4) + 2,3,4-tri-O-benzoyl-6-deoxy-L-talopyranosyl trichloroacetimidate (1260367-70-1) → 4'-O-hexanoylgenistein-7-yl-2,3,4-tri-O-benzoyl-6-deoxy-α-L-talopyranoside (1260367-71-2) + C54H52O14

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at 0 - 20 ℃; for 2h; Molecular sieve;

DOI:10.1002/cjoc.201090291

Reference yield:

5,7-Dihydroxy-3-(4-hydroxy-phenyl)-chromen-4-on (446-72-0) → 4'-O-hexanoylgenistein-7-yl-2,3,4-tri-O-benzoyl-6-deoxy-α-L-talopyranoside (1260367-71-2) + C54H52O14

Guidance literature:

Multi-step reaction with 3 steps

1: pyridine / 18 h / 0 - 20 °C

2: 1H-imidazole; thiophenol / 1-methyl-pyrrolidin-2-one / 5 h / 0 °C

3: boron trifluoride diethyl etherate / dichloromethane / 2 h / 0 - 20 °C / Molecular sieve

With pyridine; 1H-imidazole; boron trifluoride diethyl etherate; thiophenol; In 1-methyl-pyrrolidin-2-one; dichloromethane;

DOI:10.1002/cjoc.201090291

Reference yield:

5,7,4'-tri-O-hexanoyl-genistein (918158-57-3) → 4'-O-hexanoylgenistein-7-yl-2,3,4-tri-O-benzoyl-6-deoxy-α-L-talopyranoside (1260367-71-2) + C54H52O14

Guidance literature:

Multi-step reaction with 2 steps

1: 1H-imidazole; thiophenol / 1-methyl-pyrrolidin-2-one / 5 h / 0 °C

2: boron trifluoride diethyl etherate / dichloromethane / 2 h / 0 - 20 °C / Molecular sieve

With 1H-imidazole; boron trifluoride diethyl etherate; thiophenol; In 1-methyl-pyrrolidin-2-one; dichloromethane;

DOI:10.1002/cjoc.201090291

upstream raw materials:

5,4'-di-O-hexanoyl-genistein

2,3,4-tri-O-benzoyl-6-deoxy-L-talopyranosyl trichloroacetimidate

5,7,4'-tri-O-hexanoyl-genistein

2,4,4',6-tetrahydroxydeoxybenzoin

Refernces