C₃₂H₄₀Br₄NiP₂Sn₂, tetraeder

Base Information

• Chemical Name: C₃₂H₄₀Br₄NiP₂Sn₂, tetraeder
• CAS No.: 312624-41-2
• Molecular Formula: C₃₂H₄₀Br₄NiP₂Sn₂
• Molecular Weight: 1102.34
• Mol file: 312624-41-2.mol

Synonyms:

Chemical Property of C₃₂H₄₀Br₄NiP₂Sn₂, tetraeder

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₂H₄₀Br₄NiP₂Sn₂, tetraeder

There total 6 articles about C₃₂H₄₀Br₄NiP₂Sn₂, tetraeder which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.2%

{2-(bromodimethylstannyl)ethyl}diphenylphosphine (165398-04-9) + nickel dibromide (13462-88-9) → C32H40Br4NiP2Sn2, tetraeder (312624-41-2,312720-54-0)

Guidance literature:

In ethanol; all operations under dry Ar; anhydrous NiBr2 dissolved in warm dry EtOH, then soln. of Sn compd. added dropwise to this, mixt. allowed to standat room temp. for night; solvent evapd. in vac., residue crystd. by dissolving in CH2Cl2, hexaneoverlayered, filtered, dried; elem. anal.;

DOI:10.1002/1521-3749(200010)626:10<2185::AID-ZAAC2185>3.0.CO;2-F

Reference yield: 74.3%

{2-(bromodimethylstannyl)ethyl}diphenylphosphine (165398-04-9) + nickel dibromide (13462-88-9) → C32H40Br4NiP2Sn2, planar (312624-41-2,312720-54-0)

Guidance literature:

In dichloromethane; all operations under dry Ar; Sn compd. added to suspn. of anhydrous NiBr2 in CH2Cl2, mixt. refluxed for 2 d; filtered, filtrate evapd. to dryness, oily residue crystd. from CH2Cl2/hexane; elem. anal.;

DOI:10.1002/1521-3749(200010)626:10<2185::AID-ZAAC2185>3.0.CO;2-F

Reference yield:

(C6H5)2PCH2CH2Sn(CH3)3 (75271-62-4) → C32H40Br4NiP2Sn2, tetraeder (312624-41-2,312720-54-0)

Guidance literature:

Multi-step reaction with 2 steps

1: neat (no solvent, solid phase)

2: ethanol

In ethanol;

DOI:10.1002/1521-3749(200010)626:10<2185::AID-ZAAC2185>3.0.CO;2-F

upstream raw materials:

{2-(bromodimethylstannyl)ethyl}diphenylphosphine

nickel dibromide

(C₆H₅)2PCH₂CH₂Sn(CH₃)3

C₃₂H₄₀Br₄NiP₂Sn₂, planar

Downstream raw materials:

C₃₂H₄₀Br₄NiP₂Sn₂, tetraeder

Refernces