ZrCl₃{O-2,6-(CH₃)2C₆H₃}(THF)2

Base Information

• Chemical Name: ZrCl₃{O-2,6-(CH₃)2C₆H₃}(THF)2
• CAS No.: 132044-63-4
• Molecular Formula: C₁₆H₂₅Cl₃O₃Zr
• Molecular Weight: 462.956
• Mol file: 132044-63-4.mol

Synonyms:

Chemical Property of ZrCl₃{O-2,6-(CH₃)2C₆H₃}(THF)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of ZrCl₃{O-2,6-(CH₃)2C₆H₃}(THF)2

There total 2 articles about ZrCl₃{O-2,6-(CH₃)2C₆H₃}(THF)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

1,3-dimethyl-2-trimethylsilyloxybenzene (16286-54-7) + zirconium(IV) chloride (10026-11-6) → ZrCl3{O-2,6-(CH3)2C6H3}(THF)2 (132044-63-4)

Guidance literature:

With THF; In tetrahydrofuran; byproducts: Me3SiCl; Ar; equimolar ratio; -78°C; stirred at room temp. for 3 h;; evapd.; recrystd. from THF/hexane; elem. anal.;;

DOI:10.1016/0022-328X(94)80111-8

Reference yield:

zirconium tetrachloride bis(tetrahydrofuran) complex (21959-01-3,125410-70-0,125410-71-1) + 1,3-dimethyl-2-trimethylsilyloxybenzene (16286-54-7) → ZrCl3{O-2,6-(CH3)2C6H3}(THF)2 (132044-63-4)

Guidance literature:

In tetrahydrofuran; byproducts: Me3SiCl; ratio 1:1, refluxed for 6h; recrystd. (THF/hexane);

upstream raw materials:

zirconium tetrachloride bis(tetrahydrofuran) complex

1,3-dimethyl-2-trimethylsilyloxybenzene

zirconium(IV) chloride

Refernces

• 1、 Kanehisa, Nobuko,Kai, Yasushi,Kasai, Nobutami,Yasuda, Hajime,Nakayama, Yuushou,et al.. "Facile Synthesis of Group 4-6 Transition Metal Phenoxides and X-Ray Structures of TiCl22(THF)2 and NbCl32(THF)". . p. 2167 - 2170. Retrieved 2007/10/02.