bis-[(p-methoxybenzyl)cyclopentadienyl]molybdenum(IV) dichloride

Base Information

• Chemical Name: bis-[(p-methoxybenzyl)cyclopentadienyl]molybdenum(IV) dichloride
• CAS No.: 1229643-39-3
• Molecular Formula: C₂₆H₂₆Cl₂MoO₂
• Molecular Weight: 537.337
• Mol file: 1229643-39-3.mol

Synonyms:

Chemical Property of bis-[(p-methoxybenzyl)cyclopentadienyl]molybdenum(IV) dichloride

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of bis-[(p-methoxybenzyl)cyclopentadienyl]molybdenum(IV) dichloride

There total 1 articles about bis-[(p-methoxybenzyl)cyclopentadienyl]molybdenum(IV) dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.5%

LiC5H4CH2C6H4OCH3 + molybdenum(IV) chloride (13320-71-3) → bis-[(p-methoxybenzyl)cyclopentadienyl]molybdenum(IV) dichloride (1229643-39-3)

Guidance literature:

In tetrahydrofuran; byproducts: LiCl; in Schlenk flask; Li compd. in THF added via cannula to THF soln. of MoCl4; refluxed for 20 h; allowed to cool to room temp.; solvent removed under reduced pressure; washed with pentane, redissolvedin CH2Cl2, allowed to settle for 10 min; filtered through frit; solvent removed under reduced pressure, washed with pentane; elem. anal.;

DOI:10.1016/j.ica.2010.02.020

upstream raw materials:

molybdenum(IV) chloride

Refernces