bis(2-ethylhexyl) (2E)-3-[4-(methyl)phenyl]prop-2-en-1-yl phosphate

Base Information

• Chemical Name: bis(2-ethylhexyl) (2E)-3-[4-(methyl)phenyl]prop-2-en-1-yl phosphate
• CAS No.: 1542074-04-3
• Molecular Formula: C₂₆H₄₅O₄P
• Molecular Weight: 452.615
• Mol file: 1542074-04-3.mol

Synonyms:

Chemical Property of bis(2-ethylhexyl) (2E)-3-[4-(methyl)phenyl]prop-2-en-1-yl phosphate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of bis(2-ethylhexyl) (2E)-3-[4-(methyl)phenyl]prop-2-en-1-yl phosphate

There total 1 articles about bis(2-ethylhexyl) (2E)-3-[4-(methyl)phenyl]prop-2-en-1-yl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

bis(2-ethylhexyl)phosphite (3658-48-8) + p-methylcinnamyl alcohol (122058-30-4) → bis(2-ethylhexyl) (2E)-3-[4-(methyl)phenyl]prop-2-en-1-yl phosphate (1542074-04-3)

Guidance literature:

With tetrabutylammomium bromide; sodium hydroxide; In tetrachloromethane; dichloromethane; water; at 0 ℃; for 3.5h; Inert atmosphere;

DOI:10.1021/ja411869r

Reference yield:

bis(2-ethylhexyl) (2E)-3-[4-(methyl)phenyl]prop-2-en-1-yl phosphate (1542074-04-3) + trans-potassium crotonate (77485-20-2) → (+)-(1R)-1-[4-(methyl)phenyl]prop-2-en-1-yl (2E)-but-2-enoate (1542074-91-8) + C14H16O2

Guidance literature:

With C₅₈H₅₂IrNO₄P⁽¹⁺⁾; In tert-butyl methyl ether; at 20 ℃; for 8.5h; Overall yield = 80 %; Overall yield = 69.3 mg; enantioselective reaction; Inert atmosphere;

DOI:10.1021/ja411869r

upstream raw materials:

bis(2-ethylhexyl)phosphite

p-methylcinnamyl alcohol

Downstream raw materials:

(+)-(1R)-1-[4-(methyl)phenyl]prop-2-en-1-yl (2E)-but-2-enoate

Refernces