O³,O⁵-((Ξ)-benzylidene)-O¹,O²-isopropylidene-6-deoxy-β-L-idofuranose

Base Information

• Chemical Name: O³,O⁵-((Ξ)-benzylidene)-O¹,O²-isopropylidene-6-deoxy-β-L-idofuranose
• CAS No.: 34049-11-1
• Molecular Formula: C₁₆H₂₀O₅
• Molecular Weight: 292.332
• Mol file: 34049-11-1.mol

Synonyms:

Chemical Property of O³,O⁵-((Ξ)-benzylidene)-O¹,O²-isopropylidene-6-deoxy-β-L-idofuranose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of O³,O⁵-((Ξ)-benzylidene)-O¹,O²-isopropylidene-6-deoxy-β-L-idofuranose

There total 18 articles about O³,O⁵-((Ξ)-benzylidene)-O¹,O²-isopropylidene-6-deoxy-β-L-idofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

O3,O5-((Ξ)-benzylidene)-O1,O2-isopropylidene-α-D-xylo-6-deoxy-hex-5-enofuranose (19189-71-0) → O3,O5-((Ξ)-benzylidene)-O1,O2-isopropylidene-6-deoxy-β-L-idofuranose (34049-11-1)

Guidance literature:

With palladium on activated charcoal; Lindlar's catalyst; ethanol; Hydrogenation;

DOI:10.1002/hlca.19460290120

Reference yield:

O3,O5-((Ξ)-benzylidene)-O1,O2-isopropylidene-6-iodo-6-deoxy-α-D-glucofuranose (194875-04-2) → O3,O5-((Ξ)-benzylidene)-O1,O2-isopropylidene-6-deoxy-β-L-idofuranose (34049-11-1)

Guidance literature:

Multi-step reaction with 3 steps

1: liquid ammonia

2: Raney nickel; methanol / 100 °C / 95616 Torr / Hydrogenation

3: zinc chloride

With methanol; ammonia; nickel; zinc(II) chloride;

DOI:10.1002/hlca.19460290120

Reference yield:

O3,O5-((Ξ)-benzylidene)-O1,O2-isopropylidene-O6-(toluene-4-sulfonyl)-α-D-glucofuranose (7595-86-0) → O3,O5-((Ξ)-benzylidene)-O1,O2-isopropylidene-6-deoxy-β-L-idofuranose (34049-11-1)

Guidance literature:

Multi-step reaction with 4 steps

1: acetone; sodium iodide

2: liquid ammonia

3: Raney nickel; methanol / 100 °C / 95616 Torr / Hydrogenation

4: zinc chloride

With methanol; ammonia; nickel; acetone; sodium iodide; zinc(II) chloride;

DOI:10.1002/hlca.19460290120

upstream raw materials:

O³,O⁵-((Ξ)-benzylidene)-O¹,O²-isopropylidene-α-D-xylo-6-deoxy-hex-5-enofuranose

benzaldehyde

6-deoxy-1,2-O-isopropylidene-β-L-idofuranose

ethanol