potassium methyl 3-(trifluoroborato)pentanoate

Base Information

• Chemical Name: potassium methyl 3-(trifluoroborato)pentanoate
• CAS No.: 1224722-68-2
• Molecular Formula: C₆H₁₁BF₃O₂*K
• Molecular Weight: 222.057
• Mol file: 1224722-68-2.mol

Synonyms:

Chemical Property of potassium methyl 3-(trifluoroborato)pentanoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of potassium methyl 3-(trifluoroborato)pentanoate

There total 4 articles about potassium methyl 3-(trifluoroborato)pentanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(S)-methyl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pentanoate (1373154-28-9) → potassium trifluoro(1-methoxy-1-oxopentan-3-yl)borate (1224722-68-2,1327156-35-3)

Guidance literature:

With potassium hydrogenfluoride; In methanol; water; at 20 ℃; for 1h; Inert atmosphere;

Reference yield: 95.0%

potassium hydrogenfluoride (1279123-63-5) + (S)-methyl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pentanoate (1373154-28-9) → potassium trifluoro(1-methoxy-1-oxopentan-3-yl)borate (1224722-68-2,1327156-35-3)

Guidance literature:

In methanol; H₂O; react. boron compd. with KHF2 in H2O/methanol at room temp. for 1 h;

Reference yield:

C6H13BO4 → potassium methyl 3-(trifluoroborato)pentanoate (1224722-68-2,1327156-35-3)

Guidance literature:

With F₂*HK; In methanol; water; at 0 - 20 ℃;

DOI:10.1021/ol201900d

upstream raw materials:

potassium hydrogenfluoride

(S)-methyl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pentanoate

Methyl (E)-2-pentenoate

Refernces

• 1、 Lee, Jack Chang Hung,Hall, Dennis G.. "Chiral boronate derivatives via catalytic enantioselective conjugate addition of grignard reagents on 3-boronyl unsaturated esters and thioesters". . p. 5544 - 5545. Retrieved 2010/06/14.