methyl xanthoxylol

Base Information

• Chemical Name: methyl xanthoxylol
• CAS No.: 28115-69-7
• Molecular Formula: C₂₁H₂₂O₆
• Molecular Weight: 370.402
• Mol file: 28115-69-7.mol

Synonyms:

Chemical Property of methyl xanthoxylol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl xanthoxylol

There total 137 articles about methyl xanthoxylol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

Pluviatilol (28115-67-5,52151-92-5,54983-95-8,54983-96-9,62935-82-4,105661-98-1,110268-41-2,111407-29-5,92620-81-0) + methyl iodide (74-88-4) → (1R,2R,5R,6S)-2-(3,4-methylenedioxy)phenyl-6-(3,4-dimethoxy)phenyl-3,7-dioxabicyclo[3.3.0]octane (28115-69-7,31008-19-2,36150-23-9,62839-87-6,63087-37-6,63087-38-7,68296-27-5,128820-38-2,112572-28-8)

Guidance literature:

With caesium carbonate; In acetone; for 18h; Heating;

DOI:10.1021/jo035365r

Reference yield: 88.0%

1-(3,4-methylenedioxyphenyl)-1-(3-(3,4-dimethoxyphenyl)-2-propenyloxy)-2,3-epoxypropane (438581-71-6) → (+/-)-piperitol methyl ether (28115-69-7,31008-19-2,36150-23-9,62839-87-6,63087-37-6,63087-38-7,68296-27-5,112572-28-8,128820-38-2)

Guidance literature:

1-(3,4-methylenedioxyphenyl)-1-(3-(3,4-dimethoxyphenyl)-2-propenyloxy)-2,3-epoxypropane; With bis(cyclopentadienyl)titanium (III) chloride; In tetrahydrofuran; at 20 ℃; for 1h;

With iodine; In tetrahydrofuran;

DOI:10.1055/s-2001-16041

Reference yield: 75.3%

methyl thiomethylpluviatilol (97141-84-9) → (+)-Epipinoresinol (28115-69-7,31008-19-2,36150-23-9,62839-87-6,63087-37-6,63087-38-7,68296-27-5,112572-28-8,128820-38-2)

Guidance literature:

With nickel; In tetrahydrofuran; ethanol; for 4h; Heating;

upstream raw materials:

diazomethane

Pluviatilol

methyl iodide

4-methanesulfonyloxy-3-methoxybenzaldehyde

Refernces

• 1、 Alfonzo, Edwin,Beeler, Aaron B.. "A sterically encumbered photoredox catalyst enables the unified synthesis of the classical lignan family of natural products". . p. 7746 - 7754. Retrieved 2019/08/30.
• 2、 Yoda, Hidemi,Suzuki, Yuji,Matsuura, Daisuke,Takabe, Kunihiko. "A new synthetic entry to furofuranoid lignans, methyl piperitol and fargesin". . p. 519 - 522. Retrieved 2007/10/03.