C₃₁H₄₆O₁₂Si

Base Information

• Chemical Name: C₃₁H₄₆O₁₂Si
• CAS No.: 123376-94-3
• Molecular Formula: C₃₁H₄₆O₁₂Si
• Molecular Weight: 638.785
• Mol file: 123376-94-3.mol

Synonyms:

Chemical Property of C₃₁H₄₆O₁₂Si

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of C₃₁H₄₆O₁₂Si

There total 1 articles about C₃₁H₄₆O₁₂Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

2-chloroperbenzoic acid (5106-05-8) + C31H44O10Si (123376-93-2,123485-08-5) → C31H46O12Si (123376-94-3,123376-99-8,123535-83-1,123535-84-2) + C38H49ClO13Si

Guidance literature:

With sodium hydrogencarbonate; In dichloromethane; water; Ambient temperature;

DOI:10.1016/S0040-4039(00)95200-6

Reference yield:

C31H46O12Si (123376-94-3,123376-99-8,123535-83-1,123535-84-2) → (+/-)-bruceantin (41451-75-6,90397-75-4,145512-58-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 65 percent / Ag(I) oxide / acetonitrile / Heating

2: 72 percent / DCC, DMAP / CH₂Cl₂ / Ambient temperature

3: 15 percent / 3N H₂SO₄ / methanol / 29 h / Heating

With dmap; sulfuric acid; dicyclohexyl-carbodiimide; silver(l) oxide; In methanol; dichloromethane; acetonitrile;

DOI:10.1016/S0040-4039(00)95200-6

upstream raw materials:

2-chloroperbenzoic acid

C₃₁H₄₄O₁₀Si

Downstream raw materials:

(+/-)-bruceantin

Refernces