dihydro-2β,16β tabersonine

Base Information

• Chemical Name: dihydro-2β,16β tabersonine
• CAS No.: 110456-33-2
• Molecular Formula: C₂₁H₂₆N₂O₂
• Molecular Weight: 338.45
• Mol file: 110456-33-2.mol

Synonyms:

Chemical Property of dihydro-2β,16β tabersonine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dihydro-2β,16β tabersonine

There total 2 articles about dihydro-2β,16β tabersonine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

tabersonine (4429-63-4) → 2βH,3αH-tubersonine (50868-35-4) + dihydro-2β,16β tabersonine (110456-33-2)

Guidance literature:

With sodium methylate; In methanol; at 50 ℃; for 24h;

Reference yield:

→ 2,3-Dihydro-tabersonin (50868-35-4,108031-66-9,110456-33-2)

Guidance literature:

Tabersonin (Ia), Zn, HCl, Me., Rueckfl.;

Reference yield:

dihydro-2β,16β tabersonine (110456-33-2) → pachysiphine (2447-58-7)

Guidance literature:

Multi-step reaction with 4 steps

1: 2.60 g / CH₂Cl₂ / 18 h

2: 46 percent / HClO₄ 50percent, m-chloroperbenzoic acid 85percent / methanol / 18 h / in the dark

3: 55 percent / Zn / methanol / 2 h / Heating

4: 41 percent / DDQ / dioxane / 1.5 h / Heating

With perchloric acid; 3-chloro-benzenecarboperoxoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; zinc; In 1,4-dioxane; methanol; dichloromethane;

upstream raw materials:

tabersonine

Downstream raw materials:

pachysiphine

Refernces