cis-PdMePh(dppe)

Base Information

• Chemical Name: cis-PdMePh(dppe)
• CAS No.: 117308-40-4
• Molecular Formula: C₃₃H₃₂P₂Pd
• Molecular Weight: 596.985
• Mol file: 117308-40-4.mol

Synonyms:

Chemical Property of cis-PdMePh(dppe)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-PdMePh(dppe)

There total 3 articles about cis-PdMePh(dppe) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

cis-PdMePh(PMePh2)2 (117308-38-0) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → cis-PdMePh(dppe) (117308-40-4)

Guidance literature:

In diethyl ether; dichloromethane; under Ar, N2 or vac.; ligand exchange reaction; addn. of Et2O, CH2CL2 and styrene to cis-PdMePh(PMePh2)2 and dppe at -40°C; stirred 2h at 0°C; concd. almost to dryness; addn. of hexane at -70°C; pptn.; filtered; washed (Et2O); dried in vac.; dissolved in Et2O, CH2Cl2 and styrene at 10°C; allowed to stand 2 days at -20°C; pptn.; elem. anal.;

DOI:10.1021/om00103a023

Reference yield:

cis-PdMePh(PEt2Ph)2 (113530-48-6) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → cis-PdMePh(dppe) (117308-40-4)

Guidance literature:

In diethyl ether; under Ar, N2 or vac.;;

DOI:10.1021/om00103a023

Reference yield:

(1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II) (19978-61-1) + methyllithium (917-54-4) + phenyllithium (591-51-5) → cis-PdMePh(dppe) (117308-40-4)

Guidance literature:

In diethyl ether;

upstream raw materials:

(1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II)

methyllithium

phenyllithium

cis-PdMePh(PEt₂Ph)2

Refernces