N-(4-broMophenyl)hydroxylaMine

Base Information

• Chemical Name: N-(4-broMophenyl)hydroxylaMine
• CAS No.: 10468-46-9
• Molecular Formula: C6H6 Br N O
• Molecular Weight: 188.024
• Mol file: 10468-46-9.mol

Synonyms:Hydroxylamine,N-(p-bromophenyl)- (7CI,8CI); (4-Bromophenyl)hydroxylamine;(p-Bromophenyl)hydroxylamine; 4-Bromo-N-hydroxybenzenamine;N-(4-Bromophenyl)hydroxylamine; N-(p-Bromophenyl)hydroxylamine;N-Hydroxy-4-bromoaniline

Chemical Property of N-(4-broMophenyl)hydroxylaMine

Chemical Property:

• Vapor Pressure: 0.00297mmHg at 25°C
• Boiling Point: 272.4°C at 760 mmHg
• Flash Point: 118.6°C
• PSA: 32.26000
• Density: 1.772g/cm³
• LogP: 2.32320

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-(4-broMophenyl)hydroxylaMine

There total 8 articles about N-(4-broMophenyl)hydroxylaMine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

para-nitrophenyl bromide (586-78-7) → N-(4-bromophenyl)hydroxylamine (10468-46-9) + 4-bromo-aniline (106-40-1)

Guidance literature:

With Ru-Starbon; hydrazine hydrate; In methanol; at 20 ℃; for 24h; Solvent; Inert atmosphere; Green chemistry;

DOI:10.1039/c4cc09192b

Reference yield:

aniline hydrobromide (542-11-0) → 4-bromonitrosobenzene (3623-23-2) + N-(4-bromophenyl)hydroxylamine (10468-46-9) + 4-bromo-aniline (106-40-1) + 2-bromoaniline (615-36-1)

Guidance literature:

With 3,3-dimethyldioxirane; In acetone; at -65 ℃; Further byproducts given;

Reference yield:

aniline hydrobromide (542-11-0) → 4-bromonitrosobenzene (3623-23-2) + N-(4-bromophenyl)hydroxylamine (10468-46-9) + para-nitrophenyl bromide (586-78-7) + 4-bromo-aniline (106-40-1)

Guidance literature:

With 3,3-dimethyldioxirane; In acetone; at 20 ℃; for 0.0833333h;

upstream raw materials:

ethanol

4-bromonitrosobenzene

1,1-Diphenylhydrazine

para-nitrophenyl bromide

Downstream raw materials:

(Z)-N-(o-hydroxybenzylidene)-p-bromophenylamine N-oxide

4-bromo-1-phenyl-NNO-azoxybenzene

4,4'-dibromoazoxybenzene

2-(4-bromo-phenyl)-5-methyl-isoxazol-3-one

Refernces

• 1、 Jawale, Dhanaji V.,Gravel, Edmond,Boudet, Caroline,Shah, Nimesh,Geertsen, Valérie,Li, Haiyan,Namboothiri, Irishi N. N.,Doris, Eric. "Selective conversion of nitroarenes using a carbon nanotube-ruthenium nanohybrid". supporting information. p. 1739 - 1742. Retrieved 2015/03/03.
• 2、 Bhuvaneshwari,Elango. "Effect of solvent on the rate of oxidation of substituted anilines with nicotinium dichromate in aqueous-acetic acid media". . p. 999 - 1005. Retrieved 2007/10/03.