diethylammonium [N,N-bis(2,6-diisopropylphenyl)-4-(2,5-dimethylpyrrole-1-yl)benzamidinatotetrachlorotitanate]

Base Information

• Chemical Name: diethylammonium [N,N-bis(2,6-diisopropylphenyl)-4-(2,5-dimethylpyrrole-1-yl)benzamidinatotetrachlorotitanate]
• CAS No.: 1430818-46-4
• Molecular Formula: C₄H₁₂N*C₃₇H₄₆Cl₄N₃Ti
• Molecular Weight: 796.63
• Mol file: 1430818-46-4.mol

Synonyms:

Chemical Property of diethylammonium [N,N-bis(2,6-diisopropylphenyl)-4-(2,5-dimethylpyrrole-1-yl)benzamidinatotetrachlorotitanate]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diethylammonium [N,N-bis(2,6-diisopropylphenyl)-4-(2,5-dimethylpyrrole-1-yl)benzamidinatotetrachlorotitanate]

There total 3 articles about diethylammonium [N,N-bis(2,6-diisopropylphenyl)-4-(2,5-dimethylpyrrole-1-yl)benzamidinatotetrachlorotitanate] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

diethylamidotrichloridotitanium(IV) (684-55-9) + N,N'-bis(2,6-diisopropylphenyl)-4-(2,5-dimethylpyrrole-1-yl)benzamidine (1430816-31-1) → diethylammonium [N,N-bis(2,6-diisopropylphenyl)-4-(2,5-dimethylpyrrole-1-yl)benzamidinatotetrachlorotitanate] (1430818-46-4)

Guidance literature:

In toluene; at 20 ℃; for 1h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1002/ejic.201201194

Reference yield:

1-(4-Bromo-phenyl)-2,5-dimethyl-1H-pyrrole (5044-24-6) → diethylammonium [N,N-bis(2,6-diisopropylphenyl)-4-(2,5-dimethylpyrrole-1-yl)benzamidinatotetrachlorotitanate] (1430818-46-4)

Guidance literature:

Multi-step reaction with 3 steps

1.1: n-butyllithium / hexane / 4 h / -78 - 20 °C / Inert atmosphere; Schlenk technique; Glovebox

2.1: diethyl ether / -78 - 20 °C / Inert atmosphere; Schlenk technique; Glovebox

2.2: 1 h / Inert atmosphere; Schlenk technique; Glovebox

3.1: toluene / 1 h / 20 °C / Inert atmosphere; Schlenk technique; Glovebox

With n-butyllithium; In diethyl ether; hexane; toluene;

DOI:10.1002/ejic.201201194

Reference yield:

[4-(2,5-dimethyl-1H-pyrrole-1-yl)phenyl]lithium → diethylammonium [N,N-bis(2,6-diisopropylphenyl)-4-(2,5-dimethylpyrrole-1-yl)benzamidinatotetrachlorotitanate] (1430818-46-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: diethyl ether / -78 - 20 °C / Inert atmosphere; Schlenk technique; Glovebox

1.2: 1 h / Inert atmosphere; Schlenk technique; Glovebox

2.1: toluene / 1 h / 20 °C / Inert atmosphere; Schlenk technique; Glovebox

In diethyl ether; toluene;

DOI:10.1002/ejic.201201194

upstream raw materials:

1-(4-Bromo-phenyl)-2,5-dimethyl-1H-pyrrole

diethylamidotrichloridotitanium(IV)

N,N'-bis(2,6-diisopropylphenyl)-4-(2,5-dimethylpyrrole-1-yl)benzamidine

Refernces