Zincke salt

Base Information

• Chemical Name: Zincke salt
• CAS No.: 34814-24-9
• Molecular Formula: Br*C₁₁H₈N₃O₄
• Molecular Weight: 326.106
• Mol file: 34814-24-9.mol

Synonyms:

Chemical Property of Zincke salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Zincke salt

There total 1 articles about Zincke salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pyridine (110-86-1) + 2,4-dinitrobromobenzene (584-48-5) → Zincke salt (34814-24-9)

Guidance literature:

With ethanol;

Reference yield:

(1R,2R)-1,2-diaminocyclohexane (20439-47-8) + Zincke salt (34814-24-9) → C11H17N2(1+)*Br(1-) (1588442-78-7)

Guidance literature:

In dimethyl sulfoxide; at 90 ℃; for 24h; Inert atmosphere;

DOI:10.1002/ejoc.201301594 DOI:10.1002/ejoc.201301594

Reference yield:

(1R,2R)-1,2-diaminocyclohexane (20439-47-8) + Zincke salt (34814-24-9) → C18H28N3O(1+)*Br(1-) (1588442-79-8)

Guidance literature:

Multi-step reaction with 2 steps

1: dimethyl sulfoxide / 24 h / 90 °C / Inert atmosphere

2: potassium carbonate / dichloromethane / 18 h / 20 °C / Inert atmosphere

With potassium carbonate; In dichloromethane; dimethyl sulfoxide;

DOI:10.1002/ejoc.201301594 DOI:10.1002/ejoc.201301594

upstream raw materials:

pyridine

2,4-dinitrobromobenzene

Downstream raw materials:

C₁₁H₁₇N₂⁽¹⁺⁾*Br^(1-)

C₁₈H₂₈N₃O⁽¹⁺⁾*Br^(1-)