2-(1-pyrenylacetyloxy)-2'-hydroxydiphenyl sulfone

Base Information

• Chemical Name: 2-(1-pyrenylacetyloxy)-2'-hydroxydiphenyl sulfone
• CAS No.: 1332638-90-0
• Molecular Formula: C₃₀H₂₀O₅S
• Molecular Weight: 492.552
• Mol file: 1332638-90-0.mol

Synonyms:

Chemical Property of 2-(1-pyrenylacetyloxy)-2'-hydroxydiphenyl sulfone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(1-pyrenylacetyloxy)-2'-hydroxydiphenyl sulfone

There total 5 articles about 2-(1-pyrenylacetyloxy)-2'-hydroxydiphenyl sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

2,2'-dihydroxydiphenyl sulfone (15038-67-2) + 1-(bromoacetyl)pyrene (80480-15-5) → 2-(1-pyrenylacetyloxy)-2'-hydroxydiphenyl sulfone (1332638-90-0)

Guidance literature:

2,2'-dihydroxydiphenyl sulfone; With sodium methylate; In acetonitrile; for 0.5h; Reflux;

1-(bromoacetyl)pyrene; In acetonitrile; for 6h; Reflux;

DOI:10.3390/molecules16086844

Reference yield:

2,2'-dihydroxyldiphenyl sulfide (13693-59-9) → 2-(1-pyrenylacetyloxy)-2'-hydroxydiphenyl sulfone (1332638-90-0)

Guidance literature:

Multi-step reaction with 2 steps

1.1: dihydrogen peroxide; acetic acid

2.1: sodium methylate / acetonitrile / 0.5 h / Reflux

2.2: 6 h / Reflux

With dihydrogen peroxide; sodium methylate; acetic acid; In acetonitrile;

DOI:10.3390/molecules16086844

Reference yield:

2,2'-dihydroxydiphenyl sulfoxide (32568-76-6) → 2-(1-pyrenylacetyloxy)-2'-hydroxydiphenyl sulfone (1332638-90-0)

Guidance literature:

Multi-step reaction with 3 steps

1.1: acetic acid; zinc

2.1: dihydrogen peroxide; acetic acid

3.1: sodium methylate / acetonitrile / 0.5 h / Reflux

3.2: 6 h / Reflux

With dihydrogen peroxide; sodium methylate; acetic acid; zinc; In acetonitrile;

DOI:10.3390/molecules16086844

upstream raw materials:

4-bromo-phenol

2,2'-dihydroxyldiphenyl sulfide

2,2'-dihydroxydiphenyl sulfoxide

2,2'-dihydroxydiphenyl sulfone

Refernces