N-(1-ADAMANTYL)URETANE

Base Information

• Chemical Name: N-(1-ADAMANTYL)URETANE
• CAS No.: 25192-03-4
• Molecular Formula: C₁₃H₂₁NO₂
• Molecular Weight: 223.315
• Mol file: 25192-03-4.mol

Synonyms:

Chemical Property of N-(1-ADAMANTYL)URETANE

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-(1-ADAMANTYL)URETANE

There total 7 articles about N-(1-ADAMANTYL)URETANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

adamantane (281-23-2) + urethane (51-79-6) → 1-(ethoxycarbonylamino)adamantane (25192-03-4)

Guidance literature:

With nitric acid; at 30 ℃; for 1h;

DOI:10.1007/BF01455495

Reference yield: 72.0%

1-Adamantanamine (768-94-5) + chloroformic acid ethyl ester (541-41-3) → 1-(ethoxycarbonylamino)adamantane (25192-03-4)

Guidance literature:

With triethylamine; In toluene; for 6h; Heating;

DOI:10.3797/scipharm.aut-03-19

Reference yield: 71.0%

ethanol (64-17-5) + 2-(((1s,3s)-adamantan-1-yl)amino)-2-oxoacetic acid (254751-16-1) → 1-(ethoxycarbonylamino)adamantane (25192-03-4)

Guidance literature:

With tetrabutylammonium perchlorate; at 50 ℃; Temperature; Electrochemical reaction; Sealed tube; Inert atmosphere;

DOI:10.1039/d0cc05069e

upstream raw materials:

potassium cyanate

ethanol

1-nitroxyadamantane

adamantane

Downstream raw materials:

C₁₇H₂₂BrN₃O

C₁₇H₂₂ClN₃O

N-(adamantan-1-yl)hydrazinecarboxamide

Refernces

• 1、 Ogbu, Ikechukwu Martin,Lusseau, Jonathan,Kurtay, Gülbin,Robert, Frédéric,Landais, Yannick. "Urethanes synthesis from oxamic acids under electrochemical conditions". . p. 12226 - 12229. Retrieved 2020/10/26.
• 2、 Klimochkin, Yu. N.,Moiseev, I. K.. "A SIMPLE SYNTHESIS OF N-(1-ADAMANTYL)CARBAMATES". . p. 1577 - 1578. Retrieved 2007/10/02.