bis(triphenylphosphine)(pyrimidine-2-thione)copper(I) nitrate

Base Information

• Chemical Name: bis(triphenylphosphine)(pyrimidine-2-thione)copper(I) nitrate
• CAS No.: 123137-79-1
• Molecular Formula: C₄₄H₃₈CuN₄P₂S₂*NO₃
• Molecular Weight: 874.443
• Mol file: 123137-79-1.mol

Synonyms:

Chemical Property of bis(triphenylphosphine)(pyrimidine-2-thione)copper(I) nitrate

Chemical Property:

Purity/Quality:

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Technology Process of bis(triphenylphosphine)(pyrimidine-2-thione)copper(I) nitrate

There total 1 articles about bis(triphenylphosphine)(pyrimidine-2-thione)copper(I) nitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

2-thioxopyrimidine (1450-85-7) + bis(triphenylphosphane)copper(I) nitrate → bis(triphenylphosphine)(pyrimidine-2-thione)copper(I) nitrate (123137-79-1)

Guidance literature:

In ethanol; addn. of a ligand soln. in EtOH or acetone to a suspn. of Cu(PPh3)2NO3 in the same solvent (2:1 mole ratio), stirring, 40°C, 1 h; filtrated, cooled to room temp., slow evapn. of the solvent at room temp., pptn., filtered, washed (EtOH and Et2O), dried (vac.), elem. anal.;

DOI:10.1016/S0020-1693(00)83510-0

upstream raw materials:

2-thioxopyrimidine