(E)-2-hexenyl phenyl sulfone

Base Information

• Chemical Name: (E)-2-hexenyl phenyl sulfone
• CAS No.: 98830-70-7
• Molecular Formula: C₁₂H₁₆O₂S
• Molecular Weight: 224.324
• Mol file: 98830-70-7.mol

Synonyms:

Chemical Property of (E)-2-hexenyl phenyl sulfone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-2-hexenyl phenyl sulfone

There total 4 articles about (E)-2-hexenyl phenyl sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

(E)-hex-2-en-1-yl(phenyl)sulfide (98830-63-8) → (E)-2-hexenyl phenyl sulfone (98830-70-7) + [((E)-Hex-2-ene)-1-sulfinyl]-benzene

Guidance literature:

With Corynebacterium equi; at 30 ℃; for 72h; Product distribution; Other concentration;

Reference yield:

3-bromo-1-hexene (54684-73-0) + sodium benzenesulfonate (873-55-2) → (Z)-2-hexenyl phenyl sulfone (126216-30-6) + (E)-2-hexenyl phenyl sulfone (98830-70-7) + (hex-1-en-3-ylsulfonyl)benzene

Guidance literature:

With tetra-(n-butyl)ammonium iodide; In tetrahydrofuran; at 55 ℃; for 24h; Title compound not separated from byproducts;

DOI:10.1055/s-2002-20958

Reference yield:

1-hexene-3-ol (4798-44-1,67928-93-2) → (E)-2-hexenyl phenyl sulfone (98830-70-7)

Guidance literature:

Multi-step reaction with 2 steps

1: NBS; PPh₃ / tetrahydrofuran / 0.5 h / -10 - 0 °C

2: tetrabutylammonium iodide / tetrahydrofuran / 24 h / 55 °C

With N-Bromosuccinimide; tetra-(n-butyl)ammonium iodide; triphenylphosphine; In tetrahydrofuran;

DOI:10.1055/s-2002-20958

upstream raw materials:

1-hexene-3-ol

sodium benzenesulfonate

(E)-hex-2-en-1-yl(phenyl)sulfide

3-bromo-1-hexene

Refernces

• 1、 Kanai, Takaya,Kanagawa, Yoshinori,Ishii, Yasutaka. "Hydrogen Iodide Strategy for One-Pot Preparation of Allylic Azides, Nitriles, and Phenyl Sulfones from Allylic Alcohols". . p. 3274 - 3277. Retrieved 2007/10/02.