zirconium tetrafluoride

Base Information

• Chemical Name: zirconium tetrafluoride
• CAS No.: 851363-60-5
• Molecular Formula: F₄Zr
• Molecular Weight: 167.218
• Mol file: 851363-60-5.mol

Synonyms:

Chemical Property of zirconium tetrafluoride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of zirconium tetrafluoride

There total 71 articles about zirconium tetrafluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.5%

stannous fluoride + zirconium (7440-67-7) → tin (7440-31-5) + zirconium(IV) fluoride (851363-60-5,7783-64-4)

Guidance literature:

In melt; placing of mixt. of Zr with SnF2 (molar ratio SnF2:Zr=2.10) in Fluoroplast-4 ampule, closing by screwed stopper, exposition for 1.50 h at 240°C; various product ratio yields for various conditions; cooling, stirring up in water, collection, drying;

Reference yield:

Cs5Zr4F21*3H2O → zirconium(IV) fluoride (851363-60-5,7783-64-4) + cesium hexafluorozirconate + cesium fluoride (13400-13-0)

Guidance literature:

In neat (no solvent); heating up to 505°C in air with rate of 8-10 K/min; cooling; monitoring by XRD;

DOI:10.1134/S0036023609040123

Reference yield:

zirconium silicide (12039-90-6) + fluorine (7782-41-4) → zirconium(IV) fluoride (851363-60-5,7783-64-4) + silicon tetrafluoride (7783-61-1)

Guidance literature:

In neat (no solvent); warming of ZrSi2 with F2 without inflammation;;

DOI:10.1007/BF01540839

upstream raw materials:

ziconium(IV) oxychloride octahydrate

fluorine

hydrogen fluoride

zirconium(IV) oxide

Downstream raw materials:

tin(II) hexafluorozirconate

silicon tetrafluoride

tin (II) fluoride * zirconium (IV) fluoride

magnesium hexafluorozirconate

Refernces

• 1、 Kraus, Florian,Baer, Sebastian A.,Karttunen, Antti J.. "The complex amide K2[Zr(NH2)6]". . p. 1122 - 1130. Retrieved 2011/08/08.
• 2、 Godneva,Boroznovskaya,Motov,Klimkin,Mikhailova. "Thermal stability and X-ray-luminescent properties of fluorozirconates and fluorosulfatozirconates". . p. 563 - 567. Retrieved 2009/06/19.