chlorotris(4-ethylphenyl)silane

Base Information

• Chemical Name: chlorotris(4-ethylphenyl)silane
• CAS No.: 1575839-42-7
• Molecular Formula: C₂₄H₂₇ClSi
• Molecular Weight: 379.017
• Mol file: 1575839-42-7.mol

Synonyms:

Chemical Property of chlorotris(4-ethylphenyl)silane

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chlorotris(4-ethylphenyl)silane

There total 1 articles about chlorotris(4-ethylphenyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

tris(4-ethylphenyl)silane (1575839-41-6) → chlorotris(4-ethylphenyl)silane (1575839-42-7)

Guidance literature:

With sulfuryl dichloride; In tetrachloromethane; for 4h; Inert atmosphere; Reflux;

DOI:10.1021/jo402569h

Reference yield: 36.0%

4-hydroxychroman (1481-93-2) + chlorotris(4-ethylphenyl)silane (1575839-42-7) → (S)-1-tetralol (53732-47-1) + (chroman-4-yloxy)tris(4-ethylphenyl)silane + (R)-1-tetralol (23357-45-1)

Guidance literature:

4-hydroxychroman; With Levamisole; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; at -78 ℃; Inert atmosphere; Molecular sieve; Resolution of racemate;

chlorotris(4-ethylphenyl)silane; In tetrahydrofuran; at -78 ℃; for 48h; enantioselective reaction; Inert atmosphere; Molecular sieve; Resolution of racemate;

DOI:10.1021/jo402569h

Reference yield: 31.0%

1,2,3,4-Tetrahydro-1-naphthol (529-33-9) + chlorotris(4-ethylphenyl)silane (1575839-42-7) → (S)-1-tetralol (53732-47-1) + tris(4-ethylphenyl)((1,2,3,4-tetrahydronaphthalen-1-yl)oxy)-silane + (R)-1-tetralol (23357-45-1)

Guidance literature:

1,2,3,4-Tetrahydro-1-naphthol; With Levamisole; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; at -78 ℃; Inert atmosphere; Molecular sieve; Resolution of racemate;

chlorotris(4-ethylphenyl)silane; In tetrahydrofuran; at -78 ℃; for 48h; enantioselective reaction; Inert atmosphere; Molecular sieve; Resolution of racemate;

DOI:10.1021/jo402569h

upstream raw materials:

tris(4-ethylphenyl)silane

Downstream raw materials:

(S)-1-tetralol

(R)-1-tetralol

(R)-tris(4-ethylphenyl)((1,2,3,4-tetrahydronaphthalen-1-yl)oxy)-silane

Refernces