ZrCl₄(4-t-BuC₆H₄CH₂PPh₂=NC₆H₂Me₃-2,4,6)

Base Information

• Chemical Name: ZrCl₄(4-t-BuC₆H₄CH₂PPh₂=NC₆H₂Me₃-2,4,6)
• CAS No.: 388123-83-9
• Molecular Formula: C₃₂H₃₆Cl₄NPZr
• Molecular Weight: 698.654
• Mol file: 388123-83-9.mol

Synonyms:

Chemical Property of ZrCl₄(4-t-BuC₆H₄CH₂PPh₂=NC₆H₂Me₃-2,4,6)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ZrCl₄(4-t-BuC₆H₄CH₂PPh₂=NC₆H₂Me₃-2,4,6)

There total 1 articles about ZrCl₄(4-t-BuC₆H₄CH₂PPh₂=NC₆H₂Me₃-2,4,6) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

zirconium(IV) chloride (10026-11-6) + 4-t-BuC6H4CH2PPh2=NC6H2Me3-2,4,6 (388123-78-2) → ZrCl4(4-t-BuC6H4CH2PPh2=NC6H2Me3-2,4,6) (388123-83-9)

Guidance literature:

In toluene; under N2, Schlenk techniques; mixt. of ligand and ZrCl4 (molar ratio 10:1) in toluene heated to 110°C for 15 h; ppt. collected; washed with warm toluene; dried under reduced pressure for 12 h; elem. anal.;

DOI:10.1039/b105038a

Reference yield:

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + ZrCl4(4-t-BuC6H4CH2PPh2=NC6H2Me3-2,4,6) (388123-83-9) → zirconium tetrachloride bis(tetrahydrofuran) complex (21959-01-3,125410-70-0,125410-71-1)

Guidance literature:

In tetrahydrofuran; under N2, Schlenk techniques; Zr complex dissolved in THF;

DOI:10.1039/b105038a

upstream raw materials:

zirconium(IV) chloride

4-t-BuC₆H₄CH₂PPh₂=NC₆H₂Me₃-2,4,6

Downstream raw materials:

zirconium tetrachloride bis(tetrahydrofuran) complex

Refernces