[RuBr₂(PPh₃)2(sal-p-toluidine)]

Base Information

• Chemical Name: [RuBr₂(PPh₃)2(sal-p-toluidine)]
• CAS No.: 339556-81-9
• Molecular Formula: C₅₀H₄₂Br₂NOP₂Ru
• Molecular Weight: 995.715
• Mol file: 339556-81-9.mol

Synonyms:

Chemical Property of [RuBr₂(PPh₃)2(sal-p-toluidine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [RuBr₂(PPh₃)2(sal-p-toluidine)]

There total 1 articles about [RuBr₂(PPh₃)2(sal-p-toluidine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

[bis(triphenylphosphine) (methanol) ruthenium(III) tribromide] (50492-98-3,15692-71-4) + N-salicylidene-p-methylaniline (782-76-3) → [RuBr2(PPh3)2(sal-p-toluidine)] (339556-81-9)

Guidance literature:

With triethylamine; In benzene; the Schiff base (0.125 mmol) was added to a soln. of Ru-contg. compd. (0.125 mmol) in benzene; a few drops of triethylamine was added to the mixt.; refluxing for 5-6 h; under anhyd. conditions; the soln. was concd.; the complex was sepd. by the addn. of a small amt.of petroleum ether (60-80°C); recrystn. from CH2Cl2/petroleum et her; the complex was dried in vac.; elem. anal.;

upstream raw materials:

[bis(triphenylphosphine) (methanol) ruthenium(III) tribromide]

N-salicylidene-p-methylaniline

Refernces