Technology Process of 1,5-bis(2-octyldodecyl)-3,7-bis-phenylsulfanyl-5,7-dihydro-1H,3H-pyrrolo[2,3-f]ondol-2,6-dione
There total 11 articles about 1,5-bis(2-octyldodecyl)-3,7-bis-phenylsulfanyl-5,7-dihydro-1H,3H-pyrrolo[2,3-f]ondol-2,6-dione which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C50H88N2O4; thiophenol;
In
dichloromethane;
at 20 ℃;
for 15h;
With
trifluoroacetic anhydride;
In
dichloromethane;
at 20 ℃;
for 1h;
With
boron trifluoride diethyl etherate;
In
dichloromethane;
at 20 ℃;
for 2h;
DOI:10.1002/pola.26471
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: triethylamine / dichloromethane / 0 - 20 °C
2.1: potassium carbonate / tetrahydrofuran; methanol; water / 18 h / 20 °C
3.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1 h / -78 °C / Inert atmosphere
3.2: -78 - 20 °C / Inert atmosphere
4.1: dichloromethane / 15 h / 20 °C
4.2: 1 h / 20 °C
4.3: 2 h / 20 °C
With
oxalyl dichloride; potassium carbonate; dimethyl sulfoxide; triethylamine;
In
tetrahydrofuran; methanol; dichloromethane; water;
3.1: |Swern Oxidation / 3.2: |Swern Oxidation;
DOI:10.1002/pola.26471
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: potassium carbonate / tetrahydrofuran; methanol; water / 18 h / 20 °C
2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1 h / -78 °C / Inert atmosphere
2.2: -78 - 20 °C / Inert atmosphere
3.1: dichloromethane / 15 h / 20 °C
3.2: 1 h / 20 °C
3.3: 2 h / 20 °C
With
oxalyl dichloride; potassium carbonate; dimethyl sulfoxide;
In
tetrahydrofuran; methanol; dichloromethane; water;
2.1: |Swern Oxidation / 2.2: |Swern Oxidation;
DOI:10.1002/pola.26471