[(crystal violet lactone)Ru(η4-cod)]

Base Information

• Chemical Name: [(crystal violet lactone)Ru(η4-cod)]
• CAS No.: 926919-82-6
• Molecular Formula: C₃₄H₄₁N₃O₂Ru
• Molecular Weight: 624.788
• Mol file: 926919-82-6.mol

Synonyms:

Chemical Property of [(crystal violet lactone)Ru(η4-cod)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(crystal violet lactone)Ru(η4-cod)]

There total 1 articles about [(crystal violet lactone)Ru(η4-cod)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

(η6-naphthalene)(η4-1,5-cyclooctadiene)ruthenium(0) (88945-10-2) + 3,3-Bis<-(dimethylamino)phenyl>-6-(dimethylamino)-1(3H)isobenzofuranone (1552-42-7) → [(crystal violet lactone)Ru(η4-cod)] (926919-82-6)

Guidance literature:

With CH₃CN; In tetrahydrofuran; (inert conditions); stirring mixture of ruthenium compd., crystal violetlactone and acetonitrile in THF at room temp. for 2 d; concn., filtration through alumina, evapn., chromy. (alumina, toluene, then toluene-THF (25:1)), evapn., (1)H NMR;

DOI:10.1016/j.jorganchem.2006.07.046

Reference yield: 99.0%

hydrogenchloride (7647-01-0,15364-23-5) + [(crystal violet lactone)Ru(η4-cod)] (926919-82-6) → (((CH3)2NC6H4)2CHC6H3(COOH)(N(CH3)2))2Ru2Cl4 (926919-85-9)

Guidance literature:

In hydrogenchloride; acetone; (inert conditions); addn. of 4 equiv. of 1 M aqueous HCl diluted with acetone (1:20) to soln. of ruthenium compd. in acetone at -78°C, stirring for 30 min at room temp.; evapn., washing with acetone and pentane, drying under vac., ESI-MS;

DOI:10.1016/j.jorganchem.2006.07.046

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + [(crystal violet lactone)Ru(η4-cod)] (926919-82-6) → (((CH3)2NC6H4)2CC6H3(COOH)(N(CH3)2))2Ru2Cl4(2+)*2Cl(1-)=(((CH3)2NC6H4)2CC6H3(COOH)N(CH3)2)2Ru2Cl4(Cl)2

Guidance literature:

In hydrogenchloride; acetone; (inert conditions); addn. of 36.proz. aqueous HCl diluted with acetone (1:100) to soln. of ruthenium compd. in acetone at -78°C, stirringfor 6 h at -78°C; removing supernatant soln., washing with pentane, drying under vac., ESI-MS;

DOI:10.1016/j.jorganchem.2006.07.046

upstream raw materials:

(η6-naphthalene)(η4-1,5-cyclooctadiene)ruthenium(0)

3,3-Bis<-(dimethylamino)phenyl>-6-(dimethylamino)-1(3H)isobenzofuranone

Downstream raw materials:

(((CH₃)2NC₆H₄)2CHC₆H₃(COOH)(N(CH₃)2))2Ru₂Cl₄

Refernces