1-(2,2':6',2-terpyrid-4'-yl)-2,3,4,5,6-pentaphenylbenzene

Base Information

• Chemical Name: 1-(2,2':6',2-terpyrid-4'-yl)-2,3,4,5,6-pentaphenylbenzene
• CAS No.: 1004514-02-6
• Molecular Formula: C₅₁H₃₅N₃
• Molecular Weight: 689.859
• Mol file: 1004514-02-6.mol

Synonyms:

Chemical Property of 1-(2,2':6',2-terpyrid-4'-yl)-2,3,4,5,6-pentaphenylbenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(2,2':6',2-terpyrid-4'-yl)-2,3,4,5,6-pentaphenylbenzene

There total 1 articles about 1-(2,2':6',2-terpyrid-4'-yl)-2,3,4,5,6-pentaphenylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

4’-[phenylethynyl]-2,2’:6’,2’’-terpyridine (741264-92-6) + benzophenone (119-61-9) + 2,3,4,5-tetraphenylcyclopenta-2,4-dienone (479-33-4) → 1-(2,2':6',2-terpyrid-4'-yl)-2,3,4,5,6-pentaphenylbenzene (1004514-02-6)

Guidance literature:

at 280 ℃; for 7.5h; Inert atmosphere;

DOI:10.1039/c2dt30548h

Reference yield: 75.0%

dichlorobis(dimethyl sulfoxide)platinum(II) + 1-(2,2':6',2-terpyrid-4'-yl)-2,3,4,5,6-pentaphenylbenzene (1004514-02-6) → chloro(1-terpyridyl-2,3,4,5,6-pentaphenyl-benzene)platinum(II) chloride (1004514-03-7)

Guidance literature:

In methanol; ligand and Pt complex refluxed in MeOH for 24 h; Et2O added; filtered; ppt. washed with cold EtOH and Et2O; elem. anal.;

DOI:10.1021/ic700947g

Reference yield: 30.0%

potassium hexafluorophosphate (17084-13-8) + 1-(2,2':6',2-terpyrid-4'-yl)-2,3,4,5,6-pentaphenylbenzene (1004514-02-6) + ruthenium(III)chloride (10049-08-8,63767-78-2) → [Ru(1-(2,2':6',2''-terpyrid-4'-yl)-2,3,4,5,6-pentaphenylbenzene)](PF6)2

Guidance literature:

In ethanol; chloroform; terpy deriv. dissolved in EtOH/CHCl3; degassed for 30 min; RuCl3 added; mixt. flushed with Ar for 20 min; 4 drops of ethylmorpholine added, react. mixt. refluxed for 6 h, cooled, filtered, CHCl3 evapd.; KPF6 added; purified by column chromy. (Al2O3, CH3CN/aq. KNO3/H2O); elem. anal.;

DOI:10.1039/c2dt30548h

upstream raw materials:

4’-[phenylethynyl]-2,2’:6’,2’’-terpyridine

benzophenone

2,3,4,5-tetraphenylcyclopenta-2,4-dienone

Downstream raw materials:

chloro(1-terpyridyl-2,3,4,5,6-pentaphenyl-benzene)platinum(II) chloride

Refernces