(2E,4Z)-benzyl hexa-2,4-dienoate

Base Information

• Chemical Name: (2E,4Z)-benzyl hexa-2,4-dienoate
• CAS No.: 1315460-84-4
• Molecular Formula: C₁₃H₁₄O₂
• Molecular Weight: 202.253
• Mol file: 1315460-84-4.mol

Synonyms:

Chemical Property of (2E,4Z)-benzyl hexa-2,4-dienoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2E,4Z)-benzyl hexa-2,4-dienoate

There total 1 articles about (2E,4Z)-benzyl hexa-2,4-dienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzyl 3-oxohexanoate (5006-35-9) → (2E,4E)-benzyl hexa-2,4-dienoate (80313-75-3) + (2E,4Z)-benzyl hexa-2,4-dienoate (1315460-84-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: tetramethyl ammoniumhydroxide / hexane; water / 0.08 h / 5 - 10 °C

1.2: 0.17 h / 5 - 15 °C

2.1: bis(tri-t-butylphosphine)palladium⁽⁰⁾; water; sodium carbonate / toluene / 12 h / 50 °C / Inert atmosphere

With bis(tri-t-butylphosphine)palladium⁽⁰⁾; tetramethyl ammoniumhydroxide; water; sodium carbonate; In hexane; water; toluene;

DOI:10.1002/anie.201101820

upstream raw materials:

benzyl 3-oxohexanoate

Refernces