2-Methoxy ethyl formate

Base Information

• Chemical Name: 2-Methoxy ethyl formate
• CAS No.: 628-82-0
• Molecular Formula: C4H8 O3
• Molecular Weight: 104.106
• DSSTox Substance ID: DTXSID00211891
• Nikkaji Number: J96.107H
• Wikidata: Q83086885
• Mol file: 628-82-0.mol

Synonyms:2-Methoxy ethyl formate;628-82-0;Formic acid 2-methoxyethyl ester;2-methoxy-ethyl formate;SCHEMBL2660;DTXSID00211891

Chemical Property of 2-Methoxy ethyl formate

Chemical Property:

• Vapor Pressure: 13.4mmHg at 25°C
• Refractive Index: 1.38
• Boiling Point: 123.3°C at 760 mmHg
• Flash Point: 38.4°C
• PSA: 35.53000
• Density: 0.995g/cm³
• LogP: 0.44170
• XLogP3: 0
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 104.047344113
• Heavy Atom Count: 7
• Complexity: 44.2

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COCCOC=O

Technology Process of 2-Methoxy ethyl formate

There total 2 articles about 2-Methoxy ethyl formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

2-methoxy-ethanol (109-86-4,95507-80-5) + (4,6-dichloro-[1,3,5]triazin-2-yloxymethylene)-dimethyl-ammonium; fluoride → formic acid 2-methoxyethyl ester (628-82-0) + 4,6-dichloro-2-hydroxy-1,3,5-triazine (15791-08-9)

Guidance literature:

In dichloromethane; at 25 ℃; for 0.25h;

DOI:10.1021/jo0257492

Reference yield:

1,2-dimethoxyethane (110-71-4) → Methyl formate (107-31-3) + formic acid 2-methoxyethyl ester (628-82-0)

Guidance literature:

With Propanil; chlorine; at 24.85 ℃; under 760 Torr;

DOI:10.1016/S0045-6535(98)00509-8

upstream raw materials:

1,2-dimethoxyethane

2-methoxy-ethanol

Refernces

• 1、 Wenger,Porter,Collins,Treacy,Sidebottom. "Mechanisms for the chlorine atom initiated oxidation of dimethoxymethane and 1,2-dimethoxyethane in the presence of NO(x)". . p. 1197 - 1204. Retrieved 2007/10/03.