hydrido(acetato)[(S)-2,2'-bis(di-4-tolylphosphino)-1,1'-binaphthyl]chloroiridium(III)

Base Information

• Chemical Name: hydrido(acetato)[(S)-2,2'-bis(di-4-tolylphosphino)-1,1'-binaphthyl]chloroiridium(III)
• CAS No.: 888955-58-6
• Molecular Formula: C₅₀H₄₄ClIrO₂P₂
• Molecular Weight: 966.519
• Mol file: 888955-58-6.mol

Synonyms:

Chemical Property of hydrido(acetato)[(S)-2,2'-bis(di-4-tolylphosphino)-1,1'-binaphthyl]chloroiridium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hydrido(acetato)[(S)-2,2'-bis(di-4-tolylphosphino)-1,1'-binaphthyl]chloroiridium(III)

There total 1 articles about hydrido(acetato)[(S)-2,2'-bis(di-4-tolylphosphino)-1,1'-binaphthyl]chloroiridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

bis(1,5-cyclooctadiene)diiridium(I) dichloride (12112-67-3) + (+)-(R)-2,2'bis(di-para-tolylphosphanyl)-1,1'binaphthyl (153305-67-0,100165-88-6,99646-28-3) + acetic acid (64-19-7,77671-22-8) → hydrido(acetato)[(S)-2,2'-bis(di-4-tolylphosphino)-1,1'-binaphthyl]chloroiridium(III) (888955-58-6)

Guidance literature:

In toluene; under Ar; mixt. of Ir complex and binaphthyl in toluene stirred at room temp. for 6 h; acetic acid added; stirred for 15 h; volatiles removed under reduced pressure; dissolved in CH2Cl2; pptd. by adding hexane;

DOI:10.1021/om051065j

upstream raw materials:

bis(1,5-cyclooctadiene)diiridium(I) dichloride

(+)-(R)-2,2'bis(di-para-tolylphosphanyl)-1,1'binaphthyl

acetic acid

Refernces