Technology Process of 1,1,8,8-tetramesitylocta-1,2,3,4,5,6,7-heptaene
There total 10 articles about 1,1,8,8-tetramesitylocta-1,2,3,4,5,6,7-heptaene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
hydrogenchloride; tin(ll) chloride;
In
diethyl ether;
at 0 ℃;
for 0.333333h;
Inert atmosphere;
DOI:10.1002/anie.201208058
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: pyridinium chlorochromate / dichloromethane / 4 h / 20 °C / Molecular sieve
2.1: n-butyllithium / hexane; tetrahydrofuran / 0.67 h / -78 °C
2.2: 0.33 h / -78 °C
3.1: hydrogenchloride; tin(ll) chloride / diethyl ether / 0.33 h / 0 °C / Inert atmosphere
With
hydrogenchloride; n-butyllithium; pyridinium chlorochromate; tin(ll) chloride;
In
tetrahydrofuran; diethyl ether; hexane; dichloromethane;
DOI:10.1002/anie.201208058
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: silver nitrate; N-Bromosuccinimide / acetone / 3 h / 20 °C
2.1: copper(l) chloride; hydroxylamine hydrochloride; propylamine / ethanol / 12 h / 20 °C
3.1: pyridinium chlorochromate / dichloromethane / 4 h / 20 °C / Molecular sieve
4.1: n-butyllithium / hexane; tetrahydrofuran / 0.67 h / -78 °C
4.2: 0.33 h / -78 °C
5.1: hydrogenchloride; tin(ll) chloride / diethyl ether / 0.33 h / 0 °C / Inert atmosphere
With
hydrogenchloride; propylamine; N-Bromosuccinimide; n-butyllithium; hydroxylamine hydrochloride; silver nitrate; pyridinium chlorochromate; copper(l) chloride; tin(ll) chloride;
In
tetrahydrofuran; diethyl ether; ethanol; hexane; dichloromethane; acetone;
2.1: |Cadiot-Chodkiewicz Coupling;
DOI:10.1002/anie.201208058
