dimethyl(phenyl)phosphonium dithiocarboxylate

Base Information

• Chemical Name: dimethyl(phenyl)phosphonium dithiocarboxylate
• CAS No.: 116777-88-9
• Molecular Formula: C₉H₁₁PS₂
• Molecular Weight: 214.292
• Mol file: 116777-88-9.mol

Synonyms:

Chemical Property of dimethyl(phenyl)phosphonium dithiocarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dimethyl(phenyl)phosphonium dithiocarboxylate

There total 2 articles about dimethyl(phenyl)phosphonium dithiocarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + Dimethyl(phenyl)phosphine (672-66-2) → dimethyl(phenyl)phosphonium dithiocarboxylate (116777-88-9)

Guidance literature:

With diethyl ether;

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + diethyl ether (60-29-7,927820-24-4) + Dimethyl(phenyl)phosphine (672-66-2) → dimethyl(phenyl)phosphonium dithiocarboxylate (116777-88-9)

Guidance literature:

Reference yield: 88.0%

bis(tetrahydrothiophene)gold(I) perchlorate (69462-29-9) + dimethyl(phenyl)phosphonium dithiocarboxylate (116777-88-9) → bis[μ-(dimethyl(phenyl)phosphoniodithioformate-S,S')gold(I)] perchlorate

Guidance literature:

With CS₂; In dichloromethane; byproducts: tetrahydrothiophene; to cool (-20°C) CH2Cl2 soln. of (Au(C4H8S)2)ClO4 (1.6 equiv.) contg. CS2 added S2CPPhMe2 (2 equiv.), stirred for 10 min at -20°C and 10 min at room temp.; ppt. filtered off, washed with hexane; elem. anal.;

DOI:10.1039/DT9870003017

upstream raw materials:

carbon disulfide

diethyl ether

Dimethyl(phenyl)phosphine