di-t-butylchloro(mesityl)stannane

Base Information

• Chemical Name: di-t-butylchloro(mesityl)stannane
• CAS No.: 127299-03-0
• Molecular Formula: C₁₇H₂₉ClSn
• Molecular Weight: 387.58
• Mol file: 127299-03-0.mol

Synonyms:

Chemical Property of di-t-butylchloro(mesityl)stannane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of di-t-butylchloro(mesityl)stannane

There total 1 articles about di-t-butylchloro(mesityl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

mesityllithium (5806-59-7) + di-tert-butyltin dichloride (19429-30-2) → di-t-butylchloro(mesityl)stannane (127299-03-0)

Guidance literature:

In toluene; byproducts: LiCl; addn. of a petroleum ether soln. of Sn-compd. to a suspn. of mesityllithium in toluene at 10°C, stirring for 12 h at room temp., refluxing for 24 h; sepn. of LiCl, distn. in vac.;

DOI:10.1016/0022-328X(90)80110-L

Reference yield: 58.0%

di-t-butylchloro(mesityl)stannane (127299-03-0) → tri-t-butyl-2,4,6-trimethylphenylstannane (136830-53-0)

Guidance literature:

With t-butyl lithium; In pentane; byproducts: LiCl; dropwise addn. of t-BuLi soln. (n-pentane) to stannane suspn. (petroleum ether) at 0°C; stirring at 0°C, 1h, then at room temp.,24h; separation of LiCl; evapn.; crystn. (petroleum ether, -25°C); elem. anal.;

DOI:10.1016/0022-328X(91)86330-S

Reference yield: 10.0%

di-t-butylchloro(mesityl)stannane (127299-03-0) → 1,1,2,2-tetra-t-butyl-1,2-dimesityldistannane (127299-05-2)

Guidance literature:

With Na; In toluene; byproducts: NaCl; addn. of a soln. of Sn-compd. to a suspn. of Na, refluxing for 12 h; sepn. of NaCl by filtration., concg., crystn. (-25°C), recrystn. (petroleum ether 40/60), elem. anal.;

DOI:10.1016/0022-328X(90)80110-L

upstream raw materials:

mesityllithium

di-tert-butyltin dichloride

Downstream raw materials:

1,1,2,2-tetra-t-butyl-1,2-dimesityldistannane

tri-t-butyl-2,4,6-trimethylphenylstannane

Refernces