Technology Process of Toluene-4-sulfonic acid (1S,2aR,4aS,6aR,6bR)-(decahydro-cyclopenta[cd]pentalen-1-yl) ester
There total 11 articles about Toluene-4-sulfonic acid (1S,2aR,4aS,6aR,6bR)-(decahydro-cyclopenta[cd]pentalen-1-yl) ester which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 10 steps
1: LiN(i-Pr)2
2: Jones reagent
4: B2H6, H2O2
5: Jones reagent
6: SOCl2
7: 83 percent / diethyl ether / 1.) 0 deg C, 1 h; 2.) r.t., overnight
8: 83 percent / CuSO4 / toluene / 30 h / Heating
9: LiAlH4
10: pyridine
With
pyridine; lithium aluminium tetrahydride; thionyl chloride; jones reagent; dihydrogen peroxide; copper(II) sulfate; diborane; lithium diisopropyl amide;
In
diethyl ether; toluene;
DOI:10.1016/0040-4020(81)80014-2
- Guidance literature:
-
Multi-step reaction with 11 steps
2: LiN(i-Pr)2
3: Jones reagent
5: B2H6, H2O2
6: Jones reagent
7: SOCl2
8: 83 percent / diethyl ether / 1.) 0 deg C, 1 h; 2.) r.t., overnight
9: 83 percent / CuSO4 / toluene / 30 h / Heating
10: LiAlH4
11: pyridine
With
pyridine; lithium aluminium tetrahydride; thionyl chloride; jones reagent; dihydrogen peroxide; copper(II) sulfate; diborane; lithium diisopropyl amide;
In
diethyl ether; toluene;
DOI:10.1016/0040-4020(81)80014-2
- Guidance literature:
-
Multi-step reaction with 8 steps
2: B2H6, H2O2
3: Jones reagent
4: SOCl2
5: 83 percent / diethyl ether / 1.) 0 deg C, 1 h; 2.) r.t., overnight
6: 83 percent / CuSO4 / toluene / 30 h / Heating
7: LiAlH4
8: pyridine
With
pyridine; lithium aluminium tetrahydride; thionyl chloride; jones reagent; dihydrogen peroxide; copper(II) sulfate; diborane;
In
diethyl ether; toluene;
DOI:10.1016/0040-4020(81)80014-2