Ti(O-2,6-Ph₂C₆H₃)((O-2,4-Me₂C₆H₂-6-CH₂)2(OCH₂CH₂)N)

Base Information

• Chemical Name: Ti(O-2,6-Ph₂C₆H₃)((O-2,4-Me₂C₆H₂-6-CH₂)2(OCH₂CH₂)N)
• CAS No.: 1189064-07-0
• Molecular Formula: C₃₈H₃₇NO₄Ti
• Molecular Weight: 619.596
• Mol file: 1189064-07-0.mol

Synonyms:

Chemical Property of Ti(O-2,6-Ph₂C₆H₃)((O-2,4-Me₂C₆H₂-6-CH₂)2(OCH₂CH₂)N)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Ti(O-2,6-Ph₂C₆H₃)((O-2,4-Me₂C₆H₂-6-CH₂)2(OCH₂CH₂)N)

There total 1 articles about Ti(O-2,6-Ph₂C₆H₃)((O-2,4-Me₂C₆H₂-6-CH₂)2(OCH₂CH₂)N) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

titanium(IV) isopropylate (546-68-9) + (1,1';3',1''-terphenyl)-2'-ol (2432-11-3) + 2-(((2-hydroxy-3,5-dimethylbenzyl)(2-hydroxyethyl)amino)methyl)-4,6-dimethylphenol (118328-21-5) → Ti(O-2,6-Ph2C6H3)((O-2,4-Me2C6H2-6-CH2)2(OCH2CH2)N) (1189064-07-0)

Guidance literature:

In toluene; (N2) soln. phenol in toluene was added dropwise at room temp. to soln. Ti(O-i-Pr)4 in toluene, stirred for 1 h, soln. bis(2-hydroxy-3,5-dimethylbenzyl)ethanolamine in toluene was added dropwise, stirred at room temp.overnight; volatiles were removed in vacuo, toluene was added, soln. was filtered through Celite, filtrate was evapd., residue was recrystd. from toluene at -15°C; elem. anal.;

DOI:10.1021/ic9008398

upstream raw materials:

titanium(IV) isopropylate

(1,1';3',1''-terphenyl)-2'-ol

2-(((2-hydroxy-3,5-dimethylbenzyl)(2-hydroxyethyl)amino)methyl)-4,6-dimethylphenol

Refernces