Cerium(III) chloride hydrate

Base Information

• Chemical Name: Cerium(III) chloride hydrate
• CAS No.: 64332-99-6
• Molecular Formula: CeCl₃H₂O
• Molecular Weight: 264.494
• European Community (EC) Number: 811-859-3
• DSSTox Substance ID: DTXSID50892235
• Mol file: 64332-99-6.mol

Synonyms:Cerium(III) chloride hydrate;19423-76-8;trichlorocerium;hydrate;CEROUS CHLORIDE, HYDRATED;MFCD00149633;cerium(3+),trichloride,heptahydrate;cerium chloride hydrate;Cerium chloride, hydrate;Cerium trichloride monohydrate;DTXSID50892235;Cerium chloride (CeCl3), hydrate;LS-52775

Chemical Property of Cerium(III) chloride hydrate

Chemical Property:

• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 262.82257
• Heavy Atom Count: 5
• Complexity: 8

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: O.Cl[Ce](Cl)Cl

Technology Process of Cerium(III) chloride hydrate

There total 2 articles about Cerium(III) chloride hydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cerium(III) chloride heptahydrate (19423-76-8) → cerium chloride monohydrate (64332-99-6,177723-35-2,19423-76-8)

Guidance literature:

With hydrogenchloride; In neat (no solvent); byproducts: H2O; sample dehydration in fluidized bed in Pyrex glass tube in Ar/HCl gas mixt. (12-14 l/min) at 30 or 55°C; gravimetric monitoring; Kinetics;

Reference yield:

CeCl3*2H2O → cerium chloride monohydrate (64332-99-6,177723-35-2,19423-76-8)

Guidance literature:

In neat (no solvent); byproducts: H2O; sample heating at 85-100°C till the weight loss reached the calculated value; gravimetric monitoring;

DOI:10.1016/s0040-6031(98)00389-x

Reference yield: 40.0%

[CeCl3(H2O)] (177723-35-2,64332-99-6) + methyllithium (917-54-4) → methane (34557-54-5,27936-85-2) + cerium chloride (7790-86-5,15785-07-6) + lithium hydroxide (1310-65-2)

Guidance literature:

In tetrahydrofuran; (vac.);

DOI:10.1021/ja954276w

upstream raw materials:

cerium(III) chloride heptahydrate

Downstream raw materials:

cerium chloride

methane

lithium hydroxide

Refernces

• 1、 Hong, Vu Van,Sundstroem, Johan. "The dehydration schemes of rare-earth chlorides". . p. 37 - 43. Retrieved 2008/10/09.