Pt(I)(Me)(diacetyl bis(di-i-propylphenylimine))

Base Information

• Chemical Name: Pt(I)(Me)(diacetyl bis(di-i-propylphenylimine))
• CAS No.: 207456-08-4
• Molecular Formula: C₂₉H₄₃IN₂Pt
• Molecular Weight: 741.658
• Mol file: 207456-08-4.mol

Synonyms:

Chemical Property of Pt(I)(Me)(diacetyl bis(di-i-propylphenylimine))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pt(I)(Me)(diacetyl bis(di-i-propylphenylimine))

There total 1 articles about Pt(I)(Me)(diacetyl bis(di-i-propylphenylimine)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

silver tetrafluoroborate (14104-20-2) + [PtCl(Me)(diacetyl bis(2,6-diisopropylphenylimine))] (199284-91-8) + potassium iodide (7681-11-0) → Pt(I)(Me)(diacetyl bis(di-i-propylphenylimine)) (207456-08-4)

Guidance literature:

In dichloromethane; chloroform; acetonitrile; byproducts: AgCl; addn. of 1 equiv. of AgBF4 to soln. of Pt-complex, stirring for 24 h at room temp., filtration off of AgCl (Celite), evapn., dissoln (CHCl3), shaking with aq. KI; sepn. of org. layer, extn. of aq. layer (CHCl3), drying (Na2SO4), filtration, evapn.; NMR spectroscopy;

DOI:10.1021/om9800750

Reference yield: 70.0%

silver tetrafluoroborate (14104-20-2) + Pt(I)(Me)(diacetyl bis(di-i-propylphenylimine)) (207456-08-4) + acrolein (107-02-8,25068-14-8) → [PtMe(diacetyl bis(di-i-propylphenylimine))(η(2)-CH2=CHCHO)]BF4 (207456-01-7) + silver(I) iodide

Guidance literature:

In dichloromethane; N2-atmosphere; addn. of excess (6-8 equivs.) of olefin to soln. of AgBF4, addn. to soln. of Pt-complex, stirring for 5 h; filtration off of AgI (Celite), concn., pptn. on addn. of Et2O, washing (Et2O), drying (vac.); NMR spectroscopy;

DOI:10.1021/om9800750

upstream raw materials:

silver tetrafluoroborate

[PtCl(Me)(diacetyl bis(2,6-diisopropylphenylimine))]

potassium iodide

Downstream raw materials:

[PtMe(diacetyl bis(di-i-propylphenylimine))(η(2)-CH2=CHCHO)]BF4

Refernces