tetraphosphorus oxide

Base Information

• Chemical Name: tetraphosphorus oxide
• CAS No.: 114584-25-7
• Molecular Formula: OP₄
• Molecular Weight: 139.894
• Mol file: 114584-25-7.mol

Synonyms:

Chemical Property of tetraphosphorus oxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetraphosphorus oxide

There total 3 articles about tetraphosphorus oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phosphorous (12185-10-3) → phosporus oxide (14452-66-5) + diphosphorus monoxide (114584-26-8) + phosphorus dioxide (12164-97-5,12037-06-8) + tetraphosphorus oxide (114584-25-7) + tetraphosphorus oxide (114584-27-9)

Guidance literature:

With O₂; In solid matrix; byproducts: P2O5, HOPO2, HO2; codeposition of P4 vapor with Ar/O2-mixt. (50/1) at 12 K, react. with O atoms (from high-power microwave discharge, 7 h); further products;

DOI:10.1021/ja00225a001

Reference yield:

phosphorous (12185-10-3) + oxygen → phosporus oxide (14452-66-5) + diphosphorus monoxide (114584-26-8) + phosphorus dioxide (12164-97-5,12037-06-8) + tetraphosphorus oxide (114584-25-7) + tetraphosphorus oxide (114584-27-9)

Guidance literature:

In solid matrix; byproducts: P2O5, HOPO2, HO2; codeposition of P4 vapor with Ar/(16,18)O2-mixt. (50/1) at 12 K, react. with (16)O and (18)O atoms (from high-power microwave discharge, 5-9 h); further products;

DOI:10.1021/ja00225a001

Reference yield:

phosphorus (12185-10-3) + ozone (10028-15-6) → phosphorus monoxide + tetraphosphorus oxide (114584-25-7) + P4O7 (12065-80-4) + P2*OPOPO2 + P4O*O2

Guidance literature:

In solid matrix; Irradiation (UV/VIS); evapn. of phosphorus (5-10°C), codeposition with Ar/O3 at 12 K; high-pressure mercury-arc lamp irradiation: 630-1000 nm (10 min), 590-1000 nm (20 min), 420-1000 nm (20 min), 220-1000 nm (60 min) and full-arc radiation; further products; monitoring by IR spectroscopy;

upstream raw materials:

phosphorus

ozone

phosphorous

Refernces

• 1、 Andrews, Lester,Withnall, Robert. "Matrix Reactions of Oxygen Atoms with P4. Infrared Spectra of P4O, P2O, PO and PO2". . p. 5605 - 5610. Retrieved 2007/10/02.