fac-[Re(1,10-phenanthroline)(CO)₃Tbdz]

Base Information

• Chemical Name: fac-[Re(1,10-phenanthroline)(CO)₃Tbdz]
• CAS No.: 1268102-22-2
• Molecular Formula: C₂₃H₁₃N₆O₄Re
• Molecular Weight: 623.601
• Mol file: 1268102-22-2.mol

Synonyms:

Chemical Property of fac-[Re(1,10-phenanthroline)(CO)₃Tbdz]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of fac-[Re(1,10-phenanthroline)(CO)₃Tbdz]

There total 3 articles about fac-[Re(1,10-phenanthroline)(CO)₃Tbdz] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

fac-tricarbonyl(1,10-phenanthroline)bromorhenium(I) (56812-06-7,62015-31-0) + 4-(2H-tetrazol-5-yl)benzaldehyde (74815-22-8) → fac-[Re(1,10-phenanthroline)(CO)3Tbdz] (1268102-22-2)

Guidance literature:

4-(2H-tetrazol-5-yl)benzaldehyde; With triethylamine; In ethanol; Inert atmosphere;

fac-tricarbonyl(1,10-phenanthroline)bromorhenium(I); In ethanol; water; for 20h; Inert atmosphere; Reflux;

DOI:10.1021/ic402187e

Reference yield: 45.0%

fac-(1,10-phenanthroline)tricarbonylchloridorhenium(I) (52064-97-8,56846-58-3) + 4-(1H-1,2,3,4-tetrazol-5-yl)benzaldehyde (74815-22-8) → fac-[Re(1,10-phenanthroline)(CO)3Tbdz] (1268102-22-2)

Guidance literature:

With AgBF₄; (C₂H₅)3N; In acetonitrile; (N2); rhenium complex in MeCN was treated with AgBF4, soln. of tetrazoleand Et3N in MeCN was added, refluxed for 16 h; filtered through celite, concd., column chromy. (silica, CH2Cl2/MeCN, 2:3), elem. anal.;

DOI:10.1021/ic1015516

Reference yield:

fac-[Re(1,10-phenanthroline)(CO)3TbdzH][SO3CF3] (1515769-92-2) → fac-[Re(1,10-phenanthroline)(CO)3Tbdz] (1268102-22-2)

Guidance literature:

With triethylamine; In dichloromethane;

DOI:10.1021/ic402187e

upstream raw materials:

fac-(1,10-phenanthroline)tricarbonylchloridorhenium(I)

4-(1H-1,2,3,4-tetrazol-5-yl)benzaldehyde

fac-tricarbonyl(1,10-phenanthroline)bromorhenium(I)

4-(2H-tetrazol-5-yl)benzaldehyde

Refernces

• 1、 Werrett, Melissa V.,Chartrand, Daniel,Gale, Julian D.,Hanan, Garry S.,MacLellan, Jonathan G.,Massi, Massimiliano,Muzzioli, Sara,Raiteri, Paolo,Skelton, Brian W.,Silberstein, Morry,Stagni, Stefano. "Synthesis, structural, and photophysical investigation of diimine triscarbonyl Re(I) tetrazolato complexes". . p. 1229 - 1241. Retrieved 2011/04/17.