11,12-dihydrodibenzo[c,g][1,2]diazocine

Base Information

• Chemical Name: 11,12-dihydrodibenzo[c,g][1,2]diazocine
• CAS No.: 1194317-15-1
• Molecular Formula: C₁₄H₁₂N₂
• Molecular Weight: 208.263
• Mol file: 1194317-15-1.mol

Synonyms:

Chemical Property of 11,12-dihydrodibenzo[c,g][1,2]diazocine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 11,12-dihydrodibenzo[c,g][1,2]diazocine

There total 4 articles about 11,12-dihydrodibenzo[c,g][1,2]diazocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

11,12-dihydrodibenzo[c,g][1,2]diazocine-5-oxide (40754-26-5) → 11,12-dihydrodibenzo[c,g][1,2]diazocine (1194317-15-1,7092-98-0)

Guidance literature:

With bis(N,N-dimethylformamide)dichloridodioxidomolybdenum(VI); triphenylphosphine; In tetrahydrofuran; for 3h; Reflux;

DOI:10.1016/j.tet.2012.06.007 DOI:10.1016/j.tet.2012.06.007

Reference yield: 50.0%

2,2'-ethylenedianiline (34124-14-6) → 11,12-dihydrodibenzo[c,g][1,2]diazocine (1194317-15-1,7092-98-0)

Guidance literature:

With pyridine; oxygen; copper; ammonium bromide; In toluene; at 100 ℃; under 760.051 Torr;

DOI:10.1039/c4ra00749b

Reference yield:

2,2'-dinitrobibenzyl (16968-19-7) → 11,12-dihydrodibenzo[c,g][1,2]diazocine (1194317-15-1,7092-98-0)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine; formic acid; lead / methanol; water / 48 h / 20 °C / pH 9.5

2: triphenylphosphine; bis(N,N-dimethylformamide)dichloridodioxidomolybdenum(VI) / tetrahydrofuran / 3 h / Reflux

With lead; formic acid; bis(N,N-dimethylformamide)dichloridodioxidomolybdenum(VI); triethylamine; triphenylphosphine; In tetrahydrofuran; methanol; water;

DOI:10.1016/j.tet.2012.06.007 DOI:10.1016/j.tet.2012.06.007

upstream raw materials:

2,2'-dinitrobibenzyl

11,12-dihydrodibenzo[c,g][1,2]diazocine-5-oxide

5,6,11,12-tetrahydrodibenzo[c,g][1,2]diazocine

2,2'-ethylenedianiline

Refernces

• 1、 Wang, Jiaqing,He, Jing,Zhi, Cong,Luo, Bin,Li, Xinming,Pan, Yue,Cao, Xueqin,Gu, Hongwei. "Highly efficient synthesis of azos catalyzed by the common metal copper (0) through oxidative coupling reactions". . p. 16607 - 16611. Retrieved 2014/05/06.