2-PHENOXYBENZENECARBALDEHYDE OXIME

Base Information

• Chemical Name: 2-PHENOXYBENZENECARBALDEHYDE OXIME
• CAS No.: 139995-93-0
• Molecular Formula: C13H11NO2
• Molecular Weight: 0.00000
• Mol file: 139995-93-0.mol

Synonyms:

Chemical Property of 2-PHENOXYBENZENECARBALDEHYDE OXIME

Chemical Property:

• Melting Point: 87-89°C
• PSA: 0.00000
• LogP: 0.00000

Purity/Quality:

95% ^*data from raw suppliers

2-PHENOXYBENZENECARBALDEHYDE OXIME 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-PHENOXYBENZENECARBALDEHYDE OXIME

There total 5 articles about 2-PHENOXYBENZENECARBALDEHYDE OXIME which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-(phenoxy)benzaldehyde (19434-34-5) → 2-phenoxybenzaldehyde oxime (139995-93-0)

Guidance literature:

With pyridine; hydroxylamine hydrochloride; In ethanol; for 1h; Heating;

DOI:10.1039/a800868j

Reference yield:

2-(phenoxy)benzaldehyde (19434-34-5) → 2-phenoxybenzaldoxime (139995-93-0)

Guidance literature:

With hydroxylamine hydrochloride; In methanol; water;

Reference yield:

2-Fluorobenzaldehyde (446-52-6) → 2-phenoxybenzaldehyde oxime (139995-93-0)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium carbonate / N,N-dimethyl-formamide / 13 h / Reflux

2: hydroxylamine hydrochloride; sodium hydroxide / ethanol; water / 0.17 h / 20 °C

With hydroxylamine hydrochloride; potassium carbonate; sodium hydroxide; In ethanol; water; N,N-dimethyl-formamide;

DOI:10.1021/ol300125s

upstream raw materials:

2-(phenoxy)benzaldehyde

[1-(2-Phenoxy-phenyl)-meth-(E)-ylideneaminooxy]-ethaneperoxoic acid tert-butyl ester

2-Fluorobenzaldehyde

phenol

Refernces

• 1、 Keita, Massaba,Vandamme, Mathilde,Paquin, Jean-Fran?ois. "Synthesis of Nitriles from Aldoximes and Primary Amides Using XtalFluor-E". . p. 3758 - 3766. Retrieved 2015/11/28.
• 2、 Calestani, Gianluca,Leardini, Rino,McNab, Hamish,Nanni, Daniele,Zanardi, Giuseppe. "Thermal decomposition of tert-butyl o-(phenoxy)- and o-(anilino)-phenyliminoxyperacetates". . p. 1813 - 1824. Retrieved 2007/10/03.